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用树脂 201*7 从含钒废液中吸附提取和去除钒。

Extraction and removal of vanadium by adsorption with resin 201*7 from vanadium waste liquid.

机构信息

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo Henan, 454000, China.

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo Henan, 454000, China.

出版信息

Environ Res. 2020 Jan;180:108865. doi: 10.1016/j.envres.2019.108865. Epub 2019 Oct 31.

Abstract

Resin 2017 was used to extract and remove vanadium from vanadium waste liquid (VWL). More than 99% of vanadium was adsorbed from the VWL under the condition of resin dosage of 1.6 g/L, pH value of 6.0-8.0, temperature of 40 °C and adsorption time of 20 min. More than 99% of vanadium could be separated from other impurity ions in the VWL. The pure resin 2017 and loaded resin were analyzed by infrared spectroscopy. The result shows that the resin 201*7 could selectively adsorb vanadium from the VWL. The adsorption process was analyzed with adsorption kinetics and adsorption isotherm curve. The adsorption process was more fitted with pseudo-second adsorption kinetic model and the adsorption isotherm was according to Langmuir isotherm model, respectively.

摘要

树脂 2017 用于从钒废液(VWL)中提取和去除钒。在树脂用量为 1.6 g/L、pH 值为 6.0-8.0、温度为 40°C 和吸附时间为 20 min 的条件下,超过 99%的钒从 VWL 中被吸附。超过 99%的钒可以从 VWL 中的其他杂质离子中分离出来。用红外光谱法对纯树脂 2017 和负载树脂进行了分析。结果表明,树脂 201*7 可以从 VWL 中选择性地吸附钒。用吸附动力学和吸附等温线曲线对吸附过程进行了分析。吸附过程更符合拟二级吸附动力学模型,吸附等温线符合朗缪尔等温线模型,分别。

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