从保护的糖半缩醛制备 Dideoxy-1,4- 和 1,5-亚氨基戊糖醇的实用方法。
A practical approach to Dideoxy-1,4- and 1,5-iminopentitols from protected sugar hemiacetals.
机构信息
Institut de Chimie Organique et Analytique (ICOA), UMR 7311, Université d'Orléans et CNRS, Rue de Chartres, BP 6759, 45067, Orléans Cedex 2, France.
Institut de Chimie Organique et Analytique (ICOA), UMR 7311, Université d'Orléans et CNRS, Rue de Chartres, BP 6759, 45067, Orléans Cedex 2, France.
出版信息
Carbohydr Res. 2019 Dec 1;486:107855. doi: 10.1016/j.carres.2019.107855. Epub 2019 Oct 25.
The convenient and straightforward preparation of dideoxy-1,4- and 1,5-iminopentitol derivatives from protected sugar hemiacetals by way of N-tert-butanesulfinyl glycosylamines and open-chain aminoalditols is reported. The synthetic procedure is a method of choice for the making of these important scaffolds of biological interest.
本文报道了通过 N-叔丁基亚磺酰基糖基胺和开链氨基醛糖醇，从保护的糖半缩醛制备二脱氧-1,4-和 1,5-亚氨基戊糖醇衍生物的简便方法。该合成方法是制备这些具有生物意义的重要支架的首选方法。
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