Highly Selective Synthesis of Tetrahydronaphthaleno[60]fullerenes via Fullerene-Cation-Mediated Intramolecular Cyclization.
作者信息
Yang Xiao-Yu, Lin Hao-Sheng, Matsuo Yutaka
机构信息
Hefei National Laboratory for Physical Sciences at the Microscale , University of Science and Technology of China , 96 Jinzhai Road , Hefei , Anhui 230026 , China.
Department of Mechanical Engineering, School of Engineering , The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku , Tokyo 113-8656 , Japan.
出版信息
J Org Chem. 2019 Dec 20;84(24):16314-16322. doi: 10.1021/acs.joc.9b02618. Epub 2019 Dec 3.
A high-yielding protocol to construct six-membered carbon rings on fullerene is presented. This methodology with in situ fullerene-cation-mediated intramolecular cyclization provides high selectivity and efficient access to six-membered tetrahydronaphthaleno[60]fullerenes with a remarkable functional group tolerance and excellent yields. Furthermore, high solubilities of tetrahydronaphthaleno[60]fullerenes are reported.
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