Kyaw Phyu Phyu, Pongprueksa Pong, Anuchitolarn Warangkana, Sirinukunwatta Krongkarn, Suputtamongkol Kallaya
Faculty of Dentistry, Mahidol University, Rachathevi, Bangkok, Thailand.
Chemical and Biological Analysis Section, Technical Support for Material Analysis Division, National Metal and Materials Technology Center, Pathum Thani, Thailand.
J Adv Prosthodont. 2019 Oct;11(5):253-261. doi: 10.4047/jap.2019.11.5.253. Epub 2019 Oct 30.
To evaluate the influence of cyclic loading on phase transformation of zirconia abutments and to compare the effectiveness of three different quantitative ageing assessment techniques.
Thirty two Y-TZP prostheses fabricated from two brands, InCoris ZI and Ceramill ZI, were cemented to titanium bases and equally divided into two subgroups (n=8): control group without any treatment and aged group with cyclic loading between 20 N and 98 N for 100,000 cycles at 4 Hz in distilled water at 37℃. The tetragonal-to-monoclinic phase transformation was assessed by (i) conventional x-ray diffraction (XRD), (ii) micro x-ray diffraction (µXRD), and (iii) micro-Raman spectroscopy. The monoclinic-phase fractions (M%) were compared by two-way ANOVA.
InCoris Zi presented significantly higher M% than Ceramill Zi in both control and aged groups (<.001). Both materials exhibited significant phase transformation with monoclinicphase of 1 to 3% more in aged groups than controls for all thre e assessment techniques. The comparable M% was quantified by both µXRD and XRD. The highest M% was assessed with micro-Raman.
Cyclic loading produced significant phase transformation in tested Y-TZP prostheses. The micro-Raman spectroscopy could be used as an alternative to XRD and µXRD.
评估循环加载对氧化锆基台相变的影响,并比较三种不同定量老化评估技术的有效性。
用两种品牌InCoris ZI和Ceramill ZI制作的32个Y-TZP修复体粘结到钛基台上,并平均分为两个亚组(n = 8):未进行任何处理的对照组和在37℃蒸馏水中以4Hz频率在20N至98N之间循环加载100,000次的老化组。通过(i)传统X射线衍射(XRD)、(ii)微X射线衍射(µXRD)和(iii)微拉曼光谱法评估四方相向单斜相的转变。通过双向方差分析比较单斜相分数(M%)。
在对照组和老化组中,InCoris Zi的M%均显著高于Ceramill Zi(<.001)。对于所有三种评估技术,两种材料均表现出显著的相变,老化组的单斜相比对照组多1%至3%。µXRD和XRD对M%的量化结果相当。微拉曼光谱法评估的M%最高。
循环加载在测试的Y-TZP修复体中产生了显著的相变。微拉曼光谱法可作为XRD和µXRD的替代方法。