在乙酸甲酯介质中通过液相振荡制备立方相硫化钠磷（NaPS）。

Preparation of cubic NaPS by liquid-phase shaking in methyl acetate medium.

作者信息

Atsunori Matsuda, Hirotada Gamo, Phuc Nguyen Huu Huy

机构信息

Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan.

出版信息

Heliyon. 2019 Nov 14;5(11):e02760. doi: 10.1016/j.heliyon.2019.e02760. eCollection 2019 Nov.

DOI:10.1016/j.heliyon.2019.e02760

PMID:31763471

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6859230/

Abstract

Cubic NaPS (c-NaPS), a high temperature phase of NaPS, is successfully prepared by liquid-phase shaking from NaS and PS in methyl acetate medium. The effects of the amount of solvents, NaS and heat treatment on the formation of c-NaPS are carefully investigated. In addition to c-NaPS, an unknown phase is also detected in the sample containing an excess amount of NaS in the starting materials mixture.

摘要

立方相 NaPS（c-NaPS）是 NaPS 的高温相，通过在乙酸甲酯介质中由 NaS 和 PS 进行液相振荡成功制备。仔细研究了溶剂量、NaS 量和热处理对 c-NaPS 形成的影响。除了 c-NaPS 外，在起始原料混合物中含有过量 NaS 的样品中还检测到一个未知相。