Department of Physics, Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pune 411008, India.
Department of Chemistry and Centre for Quantum Information and Quantum Control, University of Toronto, 80 Saint George Street, Toronto, Ontario, Canada M5S 3H6.
Phys Rev E. 2019 Oct;100(4-1):042101. doi: 10.1103/PhysRevE.100.042101.
We use the fundamental nonequilibrium steady-state fluctuation symmetry and derive a condition on the validity of the thermodynamic uncertainty relation (TUR) in thermal transport problems, classical and quantum alike. We test this condition and study the breakdown of the TUR in different thermal transport junctions of bosonic and electronic degrees of freedom. We prove that the TUR is valid in harmonic oscillator junctions. In contrast, in the nonequilibrium spin-boson model, which realizes many-body effects, it is satisfied in the Markovian limit, but violations arise as we tune (reduce) the cutoff frequency of the thermal baths, thus observing non-Markovian dynamics. We consider heat transport by noninteracting electrons in a tight-binding chain model. We show that the TUR is feasibly violated by tuning, e.g., the hybridization energy of the chain to the metal leads. These results manifest that the validity of the TUR relies on the statistics of the participating carriers, their interaction, and the nature of their couplings to the macroscopic contacts (metal electrodes and phonon baths).
我们利用基本的非平衡定态涨落对称性,推导出热输运问题(包括经典和量子情形)中热力学不确定关系(TUR)有效性的一个条件。我们检验了这个条件,并研究了不同热输运结中玻色子和电子自由度的 TUR 破坏。我们证明 TUR 在谐振子结中是有效的。相比之下,在实现多体效应的非平衡自旋-玻色子模型中,它在马科夫极限下是满足的,但当我们调整(降低)热浴的截止频率时,会出现违反,从而观察到非马科夫动力学。我们考虑了在紧束缚链模型中非相互作用电子的热输运。我们表明,通过调整链与金属引线的杂化能等参数,TUR 是可以被违反的。这些结果表明,TUR 的有效性取决于参与载流子的统计特性、它们的相互作用以及它们与宏观接触(金属电极和声子浴)的耦合性质。