State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China.
State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China.
Ultrason Sonochem. 2020 Apr;62:104877. doi: 10.1016/j.ultsonch.2019.104877. Epub 2019 Nov 17.
Two kinds of Ti-alloys, i.e., TiMo and TiNb alloys are manufactured in this paper, and their ultrasonic cavitation erosion behaviors in 0.1 M HSO solution are evaluated by the mean depth erosion (MDE), SEM and white light photograph. The results show that MDE of TiMo and TiNb alloys obviously increase with increasing the cavitation erosion time, however, they evidently decrease with the increment of Mo or Nb content at each fixed cavitation erosion time, and even some large blank areas (uneroded areas) still exist on the sample surface after ultrasonic cavitation erosion for 2 h in the case of Ti10Mo and Ti20Nb samples, implying the enhanced anti-cavitation erosion property of Ti-alloy by adding Mo or Nb element. The MDE of Ti10Mo or Ti20Nb sample is lower than that of TC4 sample in the case of each cavitation erosion time, indicating the better cavitation erosion resistance of of Ti10Mo or Ti20Nb sample. The influences of Mo and Nb on the passivity of TiMo and TiNb alloys during the ultrasonic cavitation erosion are detected by potentiodynamic curves. The results display that Ti, TC4, TixMo (x = 1, 5, 10) and TixNb (x = 5, 10, 20) samples are all almost in the passive state within the potential region from 0V to 1.5V during ultrasonic cavitation erosion, and the passive current density evidently decreases with increasing Mo or Nb content, indicating the enhanced passive characteristic by adding Mo or Nb alloys during the ultrasonic cavitation erosion.
本文制备了两种钛合金,即 TiMo 和 TiNb 合金,并通过平均深度侵蚀(MDE)、SEM 和白光照片评估了它们在 0.1 M HSO 溶液中的超声空蚀腐蚀行为。结果表明,TiMo 和 TiNb 合金的 MDE 随着空蚀腐蚀时间的增加而明显增加,然而,在每个固定的空蚀腐蚀时间下,随着 Mo 或 Nb 含量的增加,它们明显减小,甚至在 Ti10Mo 和 Ti20Nb 样品的超声空蚀腐蚀 2 h 后,样品表面仍存在一些大的空白区域(未腐蚀区域),这表明添加 Mo 或 Nb 元素可增强钛合金的抗空蚀性能。在每种空蚀腐蚀时间下,Ti10Mo 或 Ti20Nb 样品的 MDE 均低于 TC4 样品,表明 Ti10Mo 或 Ti20Nb 样品具有更好的抗空蚀性能。通过动电位曲线检测了 Mo 和 Nb 对 TiMo 和 TiNb 合金在超声空蚀过程中钝化性的影响。结果表明,在超声空蚀过程中,Ti、TC4、TixMo(x=1、5、10)和 TixNb(x=5、10、20)样品在 0V 至 1.5V 的电位区域内几乎都处于钝化状态,并且随着 Mo 或 Nb 含量的增加,钝化电流密度明显减小,这表明在超声空蚀过程中添加 Mo 或 Nb 合金可增强其钝化特性。