State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy , Guangxi Normal University , Guilin 541004 , P. R. China.
Key Laboratory of Development and Application of Forest Chemicals of Guangxi , Guangxi University of Nationalities , Nanning 530006 , P. R. China.
Inorg Chem. 2020 Jan 6;59(1):308-314. doi: 10.1021/acs.inorgchem.9b02352. Epub 2019 Dec 6.
In this study, four in situ hydro(solvo)thermal metal-ligand reactions, including oxidation (HL), C-C coupling (HL), nitration (HL), and condensation (HL), based on bis[3-(pyridin-2-yl)-1-1,2,4-triazol-5-yl]methane (HL), in the presence of Dy ions, were carried out. The in situ metal-ligand reaction gave six new ligands existing in eight novel Dy coordination complexes, which were characterized by crystal structure, mass spectrometry, and magnetism.
在这项研究中，进行了基于双[3-(吡啶-2-基)-1H-1,2,4-三唑-5-基]甲烷（HL）的四个原位水（溶剂）热金属-配体反应，包括氧化（HL）、C-C 偶联（HL）、硝化（HL）和缩合（HL），在 Dy 离子存在下进行。原位金属-配体反应生成了六个新的配体，存在于八个新型 Dy 配合物中，这些配合物通过晶体结构、质谱和磁性进行了表征。
