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一步法将金属网转化为坚固的超疏水/超亲油网膜,用于高效的溢油清理和油水分离。

One-Step Transformation of Metal Meshes to Robust Superhydrophobic and Superoleophilic Meshes for Highly Efficient Oil Spill Cleanup and Oil/Water Separation.

机构信息

Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies , Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences , Ningbo 315201 , P. R. China.

Center of Materials Science and Optoelectronics Engineering , University of Chinese Academy of Sciences , Beijing 100049 , China.

出版信息

ACS Appl Mater Interfaces. 2020 Jan 8;12(1):1850-1857. doi: 10.1021/acsami.9b17052. Epub 2019 Dec 20.


DOI:10.1021/acsami.9b17052
PMID:31816227
Abstract

Phytic acid (PA), which is a natural and innoxious plant constituent, can strongly adsorb on the metal surface because of its six phosphate groups. In this work, based on the chelating properties of PA and the reaction between PA and hydrolyzable vinyltriethoxysilane (VTES), we developed a novel and facial strategy to generate hierarchical-layer nanospheres on the metal mesh surface and fabricated robust superhydrophobic and superoleophilic miniature metal mesh ships. Because of their superwetting properties, the modified meshes could easily remove and recycle the oil spills from the water surface (>90% collection efficiency), and have high oil/water separation capacity (>96%). The excellent stability, corrosion resistance, and robust mechanical durability endow the modified mesh ships with more advantages in a marine environment. We envision that these superhydrophobic meshes modified with PA and VTES are sustainable, environmentally friendly, and easy to scale up and hence display great potential in practical application.

摘要

植酸(PA)是一种天然无毒的植物成分,由于其具有六个磷酸基团,因此可以强烈吸附在金属表面上。在这项工作中,基于 PA 的螯合特性以及 PA 与可水解的乙烯基三乙氧基硅烷(VTES)之间的反应,我们开发了一种在金属网表面上生成分层纳米球的新颖且简便的策略,并制造了坚固的超疏水超亲油微型金属网船。由于其超润湿特性,改性网可以轻松地从水面上清除和回收溢油(>90%的收集效率),并且具有很高的油/水分离能力(>96%)。出色的稳定性,耐腐蚀性和坚固的机械耐用性使改性网船在海洋环境中具有更多优势。我们设想,这些经过 PA 和 VTES 改性的超疏水网具有可持续性,环保且易于规模化,因此在实际应用中具有很大的潜力。

相似文献

[1]
One-Step Transformation of Metal Meshes to Robust Superhydrophobic and Superoleophilic Meshes for Highly Efficient Oil Spill Cleanup and Oil/Water Separation.

ACS Appl Mater Interfaces. 2019-12-20

[2]
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[3]
One-step fabrication of eco-friendly superhydrophobic fabrics for high-efficiency oil/water separation and oil spill cleanup.

Nanoscale. 2022-1-27

[4]
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ACS Appl Mater Interfaces. 2015-11-20

[5]
Electrochemically fast preparation of superhydrophobic copper mesh for high-efficiency oil spill adsorption and oil-water separation.

J Hazard Mater. 2024-7-5

[6]
Facile fabrication of zinc oxide coated superhydrophobic and superoleophilic meshes for efficient oil/water separation.

RSC Adv. 2018-10-15

[7]
Superhydrophobic meshes that can repel hot water and strong corrosive liquids used for efficient gravity-driven oil/water separation.

Nanoscale. 2016-4-14

[8]
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ACS Appl Mater Interfaces. 2015-2-4

[9]
Femtosecond laser induced robust periodic nanoripple structured mesh for highly efficient oil-water separation.

Nanoscale. 2017-9-28

[10]
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Langmuir. 2014-1-30

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ACS Omega. 2025-5-13

[2]
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RSC Adv. 2024-6-27

[3]
Bimodal Antimicrobial Surfaces of Phytic Acid-Prussian Blue Nanoparticles-Cationic Polymer Networks.

Adv Sci (Weinh). 2023-6

[4]
Facile Construction and Fabrication of a Superhydrophobic and Super Oleophilic Stainless Steel Mesh for Separation of Water and Oil.

Nanomaterials (Basel). 2022-5-13

[5]
Superhydrophobic 304 Stainless Steel Mesh for the Removal of High-Density Polyethylene Microplastics.

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[6]
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Materials (Basel). 2021-1-19

[7]
Micro/Nanoscale Structured Superhydrophilic and Underwater Superoleophobic Hybrid-Coated Mesh for High-Efficiency Oil/Water Separation.

Polymers (Basel). 2020-6-19

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