Liang Xiong, Li Yawei, Pan Liping, Zhu Tianbin, Wang Qinghu, Li Benwen, Aneziris Christos G
The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, China.
National-provincial Joint Engineering Research Center of High Temperature Materials and Lining Technology, Wuhan, China.
Front Chem. 2019 Nov 19;7:792. doi: 10.3389/fchem.2019.00792. eCollection 2019.
Mullite reticulated porous ceramics (RPC) are one of the key components for porous media burner, the mechanical properties of mullite RPC decided the service life of the burner. However, the irregularities of cellular structure made it difficult to reveal the fracture behavior of mullite RPCs. In this study, the three-dimensional (3-D) structures of mullite RPCs were analyzed by X-ray computed tomography. The strength and damage behavior of mullite RPCs were respectively investigated via the compression tests and finite element modeling based on the actual 3-D model, also the corresponding strengthening mechanism was proposed. The results indicated that the reconstructed 3-D model exhibited the real microstructure of mullite RPCs, containing the hollow struts and strut defects. The Young's modulus calculated from actual 3-D structures was lower than that from Gibson-Ashby theory. In addition, the surface defects preceded triangular tips to generate the area of stress concentration, leading to the fracture behavior first occurred at the strut defects. With the formation of dense strut in mullite RPCs, the stress uniformly distributed in the whole solid skeleton, thus significantly improving the damage resistance of mullite RPCs.
莫来石网状多孔陶瓷(RPC)是多孔介质燃烧器的关键部件之一,莫来石RPC的力学性能决定了燃烧器的使用寿命。然而,其胞状结构的不规则性使得揭示莫来石RPC的断裂行为变得困难。在本研究中,通过X射线计算机断层扫描分析了莫来石RPC的三维(3-D)结构。基于实际的3-D模型,分别通过压缩试验和有限元模拟研究了莫来石RPC的强度和损伤行为,并提出了相应的强化机制。结果表明,重建的3-D模型展示了莫来石RPC的真实微观结构,包括空心支柱和支柱缺陷。从实际3-D结构计算得到的杨氏模量低于吉布森-阿什比理论计算值。此外,表面缺陷先于三角形尖端产生应力集中区域,导致断裂行为首先发生在支柱缺陷处。随着莫来石RPC中致密支柱的形成,应力在整个固体骨架中均匀分布,从而显著提高了莫来石RPC的抗损伤能力。