Sydoriak S G, Roberts T R, Sherman R H
Los Alamos Scientific Laboratory, University of California Los Alamos, N. Mex.
J Res Natl Bur Stand A Phys Chem. 1964 Nov-Dec;68A(6):559-565. doi: 10.6028/jres.068A.053.
An Experimental Thermodynamic Equation (ETE) temperature scale valid from 0.2 to 2.0 °K has been calculated for He. The scale is based on new comparisons, ( , ),of He and He vapor pressures above 0.9 °K; on the 1958 He temperature scale; and on the best available data for several thermodynamic properties of He from 0.2 to 2.0 °K. The Full-Range Working Equation (FWE) scale, fits the ETE scale and the ( , ) data and is therefore valid for use from 0.2 to the critical point, 3.324 °K. The maximum deviation from the ETE scale is 0.4 mdeg and the standard deviation from the input data is 0.25 mdeg. The fit to the seven recalculated isotherms of Keller in the range of the 1962 He scale can be determined by converting Keller's 's to equivalent 's, using direct to interpolation equations. The fit of the 1962 He scale is as good as the fit of the 1958 He scale to the same isotherms, the average displacements of the two scales both being 1.5 mdeg below the isotherms. The average standard deviations for ( - ) and for ( - ) are 1.2 and 1.0 mdeg, respectively, for these seven isotherms.
已针对氦气计算出了一个实验热力学方程(ETE)温标,其有效范围为0.2至2.0°K。该温标基于0.9°K以上氦气与氦气蒸气压的新比较( , );基于1958年的氦气温标;以及基于0.2至2.0°K范围内氦气几种热力学性质的现有最佳数据。全范围工作方程(FWE)温标与ETE温标及( , )数据相拟合,因此在0.2至临界点3.324°K范围内有效。与ETE温标的最大偏差为0.4毫度,与输入数据的标准偏差为0.25毫度。在1962年氦气温标的范围内,通过使用直接的 至 插值方程将凯勒的 转换为等效的 ,可以确定与凯勒重新计算的七条等温线的拟合情况。1962年氦气温标的拟合效果与1958年氦气温标对相同等温线的拟合效果一样好,两种温标的平均位移均比等温线低1.5毫度。对于这七条等温线,( - )和( - )的平均标准偏差分别为1.2毫度和1.0毫度。