赫茨自由基化学：一种获得具有多个长寿命和不同颜色氧化还原态的近红外染料的新方法。
Chemistry of Herz radicals: a new way to near-IR dyes with multiple long-lived and differently-coloured redox states.
机构信息
Institute of Organic Chemistry, Russian Academy of sciences, 630090 Novosibirsk, Russia.
出版信息
Chem Commun (Camb). 2020 Jan 16;56(5):727-730. doi: 10.1039/c9cc08557b.
PMID:31840697
Abstract
A new synthetic methodology based on the self-condensation of 1,2,3-benzodithiazolyl diradicals (Herz radicals) produces unprecedented 5-6-6-6-5 and 5-6-7-6-5 pentacyclic sulfur-nitrogen near-IR dyes featuring up to five multiple long-lived and differently coloured redox-states.
摘要
一种新的基于 1,2,3-苯并二噻唑基二自由基（Herz 自由基）自缩合的合成方法，产生了前所未有的 5-6-6-6-5 和 5-6-7-6-5 五重环硫氮近红外染料，具有多达五个多重长寿命和不同颜色的氧化还原态。
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