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单分子在周期势中的输运:带噪声的非对称简单排斥过程。

Single-file transport in periodic potentials: The Brownian asymmetric simple exclusion process.

机构信息

Universität Osnabrück, Fachbereich Physik, Barbarastraße 7, D-49076 Osnabrück, Germany.

Charles University, Faculty of Mathematics and Physics, Department of Macromolecular Physics, V Holešovičkách 2, CZ-18000 Praha 8, Czech Republic.

出版信息

Phys Rev E. 2019 Nov;100(5-1):052121. doi: 10.1103/PhysRevE.100.052121.

Abstract

Single-file Brownian motion in periodic structures is an important process in nature and technology, which becomes increasingly amenable for experimental investigation under controlled conditions. To explore and understand generic features of this motion, the Brownian asymmetric simple exclusion process (BASEP) was recently introduced. The BASEP refers to diffusion models where hard spheres are driven by a constant drag force through a periodic potential. Here we derive general properties of the rich collective dynamics in the BASEP. Average currents in the steady state change dramatically with the particle size and density. For an open system coupled to particle reservoirs, extremal current principles predict various nonequilibrium phases, which we verify by Brownian dynamics simulations. For general pair interactions we discuss connections to single-file transport by traveling-wave potentials and prove the impossibility of current reversals in systems driven by a constant drag and by traveling waves.

摘要

在周期性结构中单分子布朗运动是自然和技术中一种重要的过程,在受控条件下,这种运动越来越适合进行实验研究。为了探索和理解这种运动的一般特征,最近引入了布朗不对称简单排斥过程(BASEP)。BASEP 是指在周期性势中,硬球在恒定阻力的驱动下扩散的模型。在这里,我们推导出 BASEP 中丰富的集体动力学的一般性质。在稳态下的平均电流随粒子尺寸和密度的变化而剧烈变化。对于与粒子储库耦合的开放系统,极值电流原理预测了各种非平衡相,我们通过布朗动力学模拟验证了这一点。对于一般的对相互作用,我们讨论了与行波势中单分子输运的联系,并证明了在由恒定阻力和行波驱动的系统中不可能发生电流反转。

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