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一种使用印刷电路板(PCB)生产过程中的溶液回收 PCB 中金属的创新方法。

An innovative method of recycling metals in printed circuit board (PCB) using solutions from PCB production.

机构信息

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China.

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China; College of Humanities and Urban - Rural Development, Beijing University of Agriculture, Beijing 100096, China.

出版信息

J Hazard Mater. 2020 May 15;390:121892. doi: 10.1016/j.jhazmat.2019.121892. Epub 2019 Dec 12.

Abstract

Waste printed circuit boards (WPCBs) have both a potentially high resource value and hazardous drawbacks. Meanwhile, large quantities of corrosive waste solutions are generated in PCB production. Existing methods for recycling metals in WPCBs produce high yields but unfortunately produce secondary pollution. In this study, to minimize these disadvantages, a win-win innovative recycling method for WPCBs was developed using waste solutions that are generated in PCB production. Both of the waste solutions - waste tin stripping solution (WTSS) and waste etching solution (WES) - had an enormous capacity to extract Pb, Sn, and Cu. It was suggested that 1 L of WTSS was potentially capable for dissolving solder from 3.6 to 7.2 kg of WPCBs under room temperature, while WES was capable for Cu leaching from 0.13-0.35 kg of WPCBs. Compared with conventional leaching solutions, it was demonstrated that approximately 1 kW h of electricity could be saved from the recycling process when WTSS and WES were used to recycle only 1 kg of WPCBs. The proposed approach can be expected to significantly reduce energy consumption for recycling metals from WPCBs, without additional waste solution generated, and to increase the potential value of WTSS and WES, as they can facilitate the recycling process.

摘要

废弃印刷电路板(WPCBs)具有潜在的高资源价值和危险的缺点。同时,在 PCB 生产过程中会产生大量腐蚀性的废溶液。现有的回收 WPCBs 中金属的方法虽然产量很高,但不幸的是会产生二次污染。在这项研究中,为了最大限度地减少这些缺点,开发了一种使用 PCB 生产中产生的废溶液的双赢创新回收方法。两种废溶液——废锡剥离溶液(WTSS)和废蚀刻溶液(WES)——都具有巨大的提取 Pb、Sn 和 Cu 的能力。据推测,1L 的 WTSS 有可能在室温下溶解 3.6 至 7.2kg 的 WPCBs 中的焊料,而 WES 则能够从 0.13-0.35kg 的 WPCBs 中浸出 Cu。与传统浸出溶液相比,当仅使用 WTSS 和 WES 回收 1kg 的 WPCBs 时,回收过程可节省约 1kW·h 的电力。预计这种方法将显著降低回收 WPCBs 中金属的能源消耗,而不会产生额外的废溶液,并提高 WTSS 和 WES 的潜在价值,因为它们可以促进回收过程。

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