Danker Felix, Näther Christian, Bensch Wolfgang
Institut für Anorganische Chemie, Universität Kiel, Max-Eyth. Str. 2, 241128 Kiel, Germany.
Acta Crystallogr E Crystallogr Commun. 2020 Jan 1;76(Pt 1):32-37. doi: 10.1107/S2056989019016268.
The asymmetric unit of the title compound, {[MnSbS(CHN)]·4HO} , consists of two crystallographically independent Mn ions, two unique terpyridine ligands, one [SbS] anion and four solvent water mol-ecules, all of which are located in general positions. The [SbS] anion consists of two SbS units that share common corners. Each of the Mn ions is fivefold coordinated by two symmetry-related S atoms of [SbS] anions and three N atoms of a terpyridine ligand within an irregular coordination. Each two anions are linked by two [Mn(terpyridine)] cations into chains along the -axis direction that consist of eight-membered MnSbS4 rings. These chains are further connected into a three-dimensional network by inter-molecular O-H⋯O and O-H⋯S hydrogen bonds. The crystal investigated was twinned and therefore, a twin refinement using data in HKLF-5 [Sheldrick (2015 ▸). C, 3-8] format was performed.
标题化合物{[MnSbS(CHN)]·4HO}的不对称单元由两个晶体学独立的锰离子、两个独特的三联吡啶配体、一个[SbS]阴离子和四个溶剂水分子组成，所有这些都处于一般位置。[SbS]阴离子由两个共享公共角的SbS单元组成。每个锰离子在不规则配位中由[SbS]阴离子的两个对称相关的S原子和三联吡啶配体的三个N原子进行五配位。每两个阴离子通过两个[Mn(三联吡啶)]阳离子沿轴方向连接成链，这些链由八元MnSbS4环组成。这些链通过分子间的O-H⋯O和O-H⋯S氢键进一步连接成三维网络。所研究的晶体是孪晶，因此，使用HKLF-5[Sheldrick(2015▸). C, 3-8]格式的数据进行了孪晶精修。
