Gas-Phase Isotopic Fractionation Study of Singly and Doubly Deuterated Isotopologues of Water in the H-D Exchange Reaction by Cavity Ring-Down Spectroscopy.

The underlying mechanisms of the triple-oxygen (O, O, and O) isotopic content of deuterated (D) isotopologues of water in H-D exchange reactions in the gas phase remain elusive. Herein, we have demonstrated a high-resolution gas-phase spectral analysis of doubly (DO) and singly (HDO) deuterated isotopologues of water in the region around 7.8 μm using quantum cascade laser-based cavity ring-down spectroscopy. Isotopic fractionations among doubly and singly deuterated species of water, DO, HDO, HDO, and HDO, in the gas phase were carried out by probing the fundamental and hot band transitions in the ν (bending) mode of DO and the fundamental ν transitions for the other water isotopes. We subsequently investigated the fractionations of different D-enriched water isotopologues for the H-D exchange reaction using various mixtures of DO in HO. We explored the potential role of triple-oxygen isotopic contents through enrichments and depletions of HDO, HDO, and HDO, involved in the H-D reaction. Our first clear, direct, and quantitative experimental evidence reveals a new picture of gas-phase isotopic fractionation chemistry in a mixture of light and heavy water (HO-DO).