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用于水净化的分级TiO₂/V₂O₅多功能膜

Hierarchical TiO /V O Multifunctional Membrane for Water Purification.

作者信息

Gao Peng, Tai Ming Hang, Sun Darren Delai

机构信息

School of Civil & Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore), Fax: (+65) 67910676.

出版信息

Chempluschem. 2013 Dec;78(12):1475-1482. doi: 10.1002/cplu.201300264. Epub 2013 Sep 4.

Abstract

Membrane technology provides a new choice to solve the looming clean water scarcity crisis. However, severe membrane fouling is a great challenge in the membrane-based water treatment field. In this study, a new hierarchical TiO /V O multifunctional membrane was fabricated for the first time by assembling TiO /V O composites as a functional layer on top of the polymer supporting layer. Compared with conventional membranes, this multifunctional membrane is capable of concurrently filtering water and removing water pollutants to produce clean water without membrane fouling. Hence, this membrane can sustain high permeate flux for a longer period. These virtues can be attributed to the following reasons, among others: 1) low resistance of the nanofibrous functional layer, 2) enhanced light absorption and scattering of the hierarchical nanostructure, and 3) facilitated charge separation owing to the heterojunctions between TiO and V O . This novel membrane opens up a new avenue for the fabrication of a next-generation multifunctional membrane.

摘要

膜技术为解决迫在眉睫的清洁水短缺危机提供了新的选择。然而,严重的膜污染是基于膜的水处理领域面临的巨大挑战。在本研究中,首次通过将TiO₂/V₂O₅复合材料组装在聚合物支撑层顶部作为功能层,制备了一种新型的分级TiO₂/V₂O₅多功能膜。与传统膜相比,这种多功能膜能够同时过滤水和去除水中污染物,从而生产出无膜污染的清洁水。因此,这种膜能够在较长时间内维持较高的渗透通量。这些优点可归因于以下几个原因:1)纳米纤维功能层的低阻力;2)分级纳米结构增强的光吸收和散射;3)TiO₂和V₂O₅之间的异质结促进了电荷分离。这种新型膜为下一代多功能膜的制备开辟了一条新途径。

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