Mou Nanli, Liu Xiaolong, Wei Tao, Dong Hongxing, He Qiong, Zhou Lei, Zhang Yaqiang, Zhang Long, Sun Shulin
Key Laboratory of Materials for High-Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800, China.
Nanoscale. 2020 Mar 7;12(9):5374-5379. doi: 10.1039/c9nr07602f. Epub 2020 Jan 29.
Metamaterial-based electromagnetic absorbers have attracted much attention recently, but most previous realizations suffer from issues of narrow bandwidth, time-consuming and high-cost fabrication methods, and/or fixed functionalities, and so are unfavorable for practical applications. Here, we demonstrate experimentally a large-scale, broadband, polarization-independent, and tunable metamaterial absorber, which works for both visible and near-infrared light. A lithography-free and low-cost method was utilized to fabricate a centimeter-sized metamaterial sample in a metal-insulator-metal (MIM) configuration with nano-scale precision, in which a phase-change material, GeSbTe (GST), was adopted as the insulating spacer of the MIM structure. With two different resonance mechanisms working together, the proposed device was shown to exhibit high absorptivity (>80%) within a broad wavelength band (480-1020 nm). By thermally tuning the phase state of the GST layer, we can dramatically enlarge the working bandwidth of the metamaterial absorber by shifting one absorption peak by about 470 nm. These findings may stimulate many potential applications in, for example, solar cells, energy harvesting, smart sensing/imaging, and color printing.
基于超材料的电磁吸收器近来备受关注,但此前的大多数实现方式都存在带宽窄、制造方法耗时且成本高以及/或者功能固定等问题,因此不利于实际应用。在此,我们通过实验展示了一种大规模、宽带、偏振无关且可调谐的超材料吸收器,其适用于可见光和近红外光。我们采用了一种无需光刻且成本低的方法,以纳米级精度制造了厘米尺寸的金属-绝缘体-金属(MIM)结构的超材料样品,其中采用相变材料锗锑碲(GST)作为MIM结构的绝缘间隔层。通过两种不同的共振机制共同作用,所提出的器件在宽波长范围(480 - 1020 nm)内表现出高吸收率(>80%)。通过热调谐GST层的相态,我们可以通过将一个吸收峰移动约470 nm来显著扩大超材料吸收器的工作带宽。这些发现可能会激发许多潜在应用,例如太阳能电池、能量收集、智能传感/成像以及彩色印刷等领域。