Departamento de Ingeniería Química, Universidad Nacional del Sur, (UNS), Bahía Blanca, Argentina.
Planta Piloto de Ingeniería Química - PLAPIQUI (UNS-CONICET), Bahía Blanca, Argentina.
J Sci Food Agric. 2020 Apr;100(6):2675-2687. doi: 10.1002/jsfa.10298. Epub 2020 Feb 21.
Edible films were obtained from aqueous emulsions prepared with low-methoxyl pectin at different concentrations (10, 20 and 30 g kg ) and two sunflower wax samples recovered from two waste samples of filter cakes produced in the winterization process of sunflower oil. The two sunflower waxes samples recovered (from the normal hybrid, NSFW, and from the high-oleic hybrid, HOSFW) were added in three proportions (0.1, 0.2 and 0.3 g g of pectin). Films were evaluated according to their structure, water resistance, water vapor permeability, mechanical properties and thermal behavior.
In general, good dispersion of the lipid material was observed in the cross-sections of the film. Increase in the water resistance (lower swelling index and water adsorption) was associated with a greater pectin content crosslinked with Ca and the hydrophobic nature of waxes. The reduction in water vapor transfer rates was influenced by the effect of the wax addition, their fatty acid composition and their good distribution on the film. More resistant, rigid and less flexible films were obtained with lower pectin content, finding an inverse relationship between tensile strength and elongation percentage values.
These results evidence a promising alternative in the development of innovative strategies to valorize sunflower waxes derived from waste material. © 2020 Society of Chemical Industry.
可食用薄膜是由低甲氧基果胶在不同浓度(10、20 和 30 g kg)下制备的水乳液和从葵花籽油冬化过程中产生的两个滤饼废物中回收的两种葵花蜡样品制成的。回收的两种葵花蜡样品(来自普通杂交种 NSFW 和高油酸杂交种 HOSFW)以三种比例(0.1、0.2 和 0.3 g g 果胶)添加。根据其结构、耐水性、水蒸气透过性、机械性能和热行为对薄膜进行了评估。
一般来说,在薄膜的横截面中观察到脂质材料的良好分散。耐水性(较低的溶胀指数和吸水率)的增加与更多的果胶交联与 Ca 以及蜡的疏水性有关。水蒸气传递速率的降低受蜡添加、其脂肪酸组成及其在薄膜上良好分布的影响。通过降低果胶含量,可以获得更具弹性、刚性和柔韧性较低的薄膜,发现拉伸强度和伸长率值之间存在反比关系。
这些结果为开发利用来自废物的创新策略来增值葵花蜡提供了有希望的替代方案。 © 2020 化学工业协会。