四面体笼状结构的阴离子配位驱动组装中的手性转录
Chirality transcription in the anion-coordination-driven assembly of tetrahedral cages.
作者信息
Fu Jin, Zheng Bo, Zhang Huizheng, Zhao Yanxia, Zhang Dan, Zhang Wenyao, Yang Xiao-Juan, Wu Biao
机构信息
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China.
出版信息
Chem Commun (Camb). 2020 Feb 25;56(16):2475-2478. doi: 10.1039/c9cc09752j.
PMID:31998905
Abstract
Enantiopure A4L4 tetrahedral cages (either ΔΔΔΔ or ΛΛΛΛ) were obtained through the anion-coordination-driven assembly (ACDA) of phosphate anions with C3-symmetric tris-bis(urea) ligands bearing chiral groups.
摘要
通过具有手性基团的 C3 对称三双（脲）配体与磷酸根阴离子的阴离子配位驱动组装（ACDA）获得了对映体纯的 A4L4 四面体笼（ΔΔΔΔ 或 ΛΛΛΛ）。
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