Fu Jin, Zheng Bo, Zhang Huizheng, Zhao Yanxia, Zhang Dan, Zhang Wenyao, Yang Xiao-Juan, Wu Biao
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China.
Chem Commun (Camb). 2020 Feb 25;56(16):2475-2478. doi: 10.1039/c9cc09752j.
Enantiopure A4L4 tetrahedral cages (either ΔΔΔΔ or ΛΛΛΛ) were obtained through the anion-coordination-driven assembly (ACDA) of phosphate anions with C3-symmetric tris-bis(urea) ligands bearing chiral groups.
通过具有手性基团的 C3 对称三双（脲）配体与磷酸根阴离子的阴离子配位驱动组装（ACDA）获得了对映体纯的 A4L4 四面体笼（ΔΔΔΔ 或 ΛΛΛΛ）。
