一种基于杯[4]间苯二酚芳烃的巨型配位笼：可控组装与碘摄取
A calix[4]resorcinarene-based giant coordination cage: controlled assembly and iodine uptake.
作者信息
Pei Wen-Yuan, Yang Jin, Wu Hui, Zhou Wei, Yang Ying-Wei, Ma Jian-Fang
机构信息
Key Lab for Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, China.
出版信息
Chem Commun (Camb). 2020 Feb 25;56(16):2491-2494. doi: 10.1039/d0cc00157k.
Abstract
Construction of large multi-component coordination cages becomes much more challenging as the number of building blocks increases. A giant hexameric calix[4]resorcinarene-based coordination cage (cage-1) was successfully designed through the precise tuning of ancillary rigid tetracarboxylic acid. Significantly, cage-1 exhibited reversible uptake of volatile iodine, suggesting that it could serve as a porous material for efficient capture and separation of radioactive iodine.
摘要
随着构建模块数量的增加，构建大型多组分配位笼变得更具挑战性。通过对辅助刚性四羧酸进行精确调控，成功设计出一种基于杯[4]间苯二酚的巨型六聚体配位笼（笼-1）。值得注意的是，笼-1对挥发性碘具有可逆吸收作用，这表明它可作为一种多孔材料用于高效捕获和分离放射性碘。
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1
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Chem Commun (Camb). 2019 May 28;55(44):6277-6280. doi: 10.1039/c9cc01828j.
2
Self-assembly of tetravalent Goldberg polyhedra from 144 small components.由144个小部件自组装而成的四价戈德堡多面体。
Nature. 2016 Dec 21;540(7634):563-566. doi: 10.1038/nature20771.
3
Controlling the Recognition and Reactivity of Alkyl Ammonium Guests Using an Anion Coordination-Based Tetrahedral Cage.利用基于阴离子配位的四面体笼控制烷基铵客体的识别和反应性。
J Am Chem Soc. 2018 Apr 18;140(15):5248-5256. doi: 10.1021/jacs.8b01488. Epub 2018 Apr 10.
4
Self-Assembly of Chiral Metal-Organic Tetartoid.手性金属-有机四面体形的自组装。
J Am Chem Soc. 2018 Jan 10;140(1):118-121. doi: 10.1021/jacs.7b11285. Epub 2017 Dec 18.
5
Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks.碘分子在坚固的金属有机骨架内被限制在三螺旋链中。
J Am Chem Soc. 2017 Nov 15;139(45):16289-16296. doi: 10.1021/jacs.7b08748. Epub 2017 Nov 3.
6
Stereochemical plasticity modulates cooperative binding in a CoL cuboctahedron.立体化学塑性调节 CoL 立方八面体中的协同结合。
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7
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8
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9
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10
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