Pawlak Mariusz, Szidarovszky Tamás, Halász Gábor J, Vibók Ágnes
Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland.
Laboratory of Molecular Structure and Dynamics, Institute of Chemistry, ELTE Eötvös Loránd University and MTA-ELTE Complex Chemical Systems Research Group, Pázmány Péter sétány 1/A, H-1117 Budapest, Hungary.
Phys Chem Chem Phys. 2020 Feb 14;22(6):3715-3723. doi: 10.1039/c9cp06587c. Epub 2020 Jan 31.
The absorption spectra of the cold Na molecule dressed by a linearly polarized standing laser wave is investigated with a theoretical model incorporating translational, electronic, vibrational as well as rotational degrees of freedom. In such a situation a light-induced conical intersection (LICI) can be formed (J. Phys. B: At. Mol. Opt. Phys., 2008, 41, 221001). To measure the spectra a weak field is used whose propagation direction is perpendicular to the direction of the dressing field but has identical polarization direction. Although LICIs are present in our model, the simulations demonstrate a very robust absorption spectrum, which is insensitive to the intensity and the wavelength of the dressing field and which does not reflect clear signatures of light-induced nonadiabatic phenomena related to the strong mixing between the electronic, vibrational, rotational and translational motions. However, by widening artificially the very narrow translational energy level gaps, the fingerprint of the LICI appears to some extent in the spectrum.
利用一个包含平动、电子、振动以及转动自由度的理论模型,研究了由线偏振驻波激光修饰的冷钠分子的吸收光谱。在这种情况下,可能会形成光诱导锥形交叉点(LICI)(《物理学报B:原子、分子和光学物理》,2008年,41卷,221001)。为了测量光谱,使用了一个弱场,其传播方向垂直于修饰场的方向,但偏振方向相同。尽管我们的模型中存在LICI,但模拟结果显示出一个非常稳健的吸收光谱,该光谱对修饰场的强度和波长不敏感,并且没有反映出与电子、振动、转动和平动运动之间的强混合相关的光诱导非绝热现象的清晰特征。然而,通过人为地拓宽非常窄的平动能级间隙,LICI的指纹在光谱中在一定程度上出现了。