State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China.
Mechanical & Nuclear Engineering Department, University of Sharjah, PO Box 27272, Sharjah, United Arab Emirates.; Sustainable Energy Development Research Group, Research Institute of Sciences and Engineering (RISE), University of Sharjah, Sharjah, United Arab Emirates.
Sci Total Environ. 2020 May 1;715:136849. doi: 10.1016/j.scitotenv.2020.136849. Epub 2020 Jan 22.
The combustion of conventional fuels within the transportation sector is a crucial driver of global warming and produces a number of harmful emissions. To decrease these adverse factors, the development of synthetic fuels produced from renewable energy sources via the catalytic conversion of carbon dioxide (CO) and hydrogen (H) has progressed significantly. Eco-friendly fuels have a reduced impact on the environment throughout their production and use cycles. In recent years, the use of polyoxymethylene dimethyl ethers (PODE) as fuels has received an increasing amount of attention, owing to their engine performance and reduced environmental impact. The specific target of this paper is to systematically review the field of PODE application-based additives as fuel for internal combustion engines. The background and highlights of current and future applications of PODE are also discussed, and the challenges associated with the use of this additive are also briefly reviewed. A number of studies have shown that the use of fuel mixtures with up to 10% PODE can have a significant impact on the reduction of engine emissions. PODE have been shown to reduce the emissions of soot, particulates, CO, and HC under different parameters and working conditions, although NO and brake-specific fuel consumption (BSFC) emissions have been found to increase. Additionally, PODE can be produced from natural gas or electric power via CO activation in a sustainable manner, which represents a significant benefit with regard to the use of oil-based products. Finally, fossil fuels blended with PODE can be easily ignited and burned at stoichiometric conditions.
在交通运输领域,传统燃料的燃烧是全球变暖的一个关键驱动因素,同时产生了许多有害排放物。为了减少这些不利因素,通过二氧化碳(CO)和氢气(H)的催化转化来开发由可再生能源生产的合成燃料已经取得了显著进展。在其生产和使用周期中,环保燃料对环境的影响较小。近年来,聚甲醛二甲醚(PODE)作为燃料的使用受到了越来越多的关注,因为其具有发动机性能和降低环境影响的特点。本文的具体目标是系统地回顾基于 PODE 应用添加剂作为内燃机燃料的领域。还讨论了 PODE 当前和未来应用的背景和重点,以及使用这种添加剂所面临的挑战。许多研究表明,使用高达 10% PODE 的燃料混合物可以显著降低发动机排放。已经证明,PODE 可以在不同的参数和工作条件下减少烟尘、颗粒物、CO 和 HC 的排放,尽管发现 NO 和比油耗(BSFC)排放增加了。此外,PODE 可以通过 CO 激活以可持续的方式从天然气或电力中生产,这在使用基于油的产品方面具有重要意义。最后,化石燃料与 PODE 的混合物可以在化学计量条件下轻松点燃和燃烧。