Akai Takashi, Blunt Martin J, Bijeljic Branko
Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK.
Department of Earth Science and Engineering, Imperial College London, SW7 2BP, UK.
J Colloid Interface Sci. 2020 Apr 15;566:444-453. doi: 10.1016/j.jcis.2020.01.065. Epub 2020 Jan 22.
The change of wettability toward more water-wet by the injection of low salinity water can improve oil recovery from porous rocks, which is known as low salinity water flooding. To simulate this process at the pore-scale, we propose that the alteration in surface wettability mediated by thin water films which are below the resolution of simulation grid blocks has to be considered, as observed in experiments. This is modeled by a wettability alteration model based on rate-limited adsorption of ions onto the rock surface.
The wettability alteration model is developed and incorporated into a lattice Boltzmann simulator which solves both the Navier-Stokes equation for oil/water two-phase flow and the advection-diffusion equation for ion transport. The model is validated against two experiments in the literature, then applied to 3D micro-CT images of a rock.
Our model correctly simulated the experimental observations caused by the slow wettability alteration driven by the development of water films. In the simulations on the 3D rock pore structure, a distinct difference in the mixing of high and low salinity water is observed between secondary and tertiary low salinity flooding, resulting in different oil recoveries.
注入低盐水使润湿性向更亲水方向转变可提高多孔岩石的原油采收率,这一过程被称为低盐水驱油。为了在孔隙尺度上模拟这一过程,我们提出,正如实验中所观察到的那样,必须考虑由低于模拟网格块分辨率的薄水膜介导的表面润湿性变化。这通过基于离子在岩石表面的限速吸附的润湿性变化模型进行建模。
开发了润湿性变化模型,并将其纳入格子玻尔兹曼模拟器,该模拟器可求解油/水两相流的纳维-斯托克斯方程和离子输运的平流-扩散方程。该模型针对文献中的两个实验进行了验证,然后应用于一块岩石的三维显微CT图像。
我们的模型正确地模拟了由水膜形成驱动的缓慢润湿性变化所导致的实验观测结果。在对三维岩石孔隙结构的模拟中,二次和三次低盐水驱油之间在高、低盐水混合方面存在明显差异,从而导致不同的原油采收率。