Tan Che, Liu Zhendong, Yonezawa Yasuo, Sukenaga Sohei, Ando Mariko, Shibata Hiroyuki, Sasaki Yukichi, Okubo Tatsuya, Wakihara Toru
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Chem Commun (Camb). 2020 Mar 4;56(18):2811-2814. doi: 10.1039/c9cc09966b. Epub 2020 Feb 7.
The function of pressure has long been overlooked in the hydrothermal synthesis of zeolites, which is typically carried out under an autogenous pressure (below 2 MPa). We herein report, the first of its kind, a detailed investigation on the hydrothermal synthesis of zeolites under external high pressures, where crystallization behaviors contradicting the common observations were generated.
压力的作用在沸石的水热合成中长期被忽视,沸石的水热合成通常在自生压力(低于2兆帕)下进行。我们在此首次报道了对外部高压下沸石水热合成的详细研究,在该研究中产生了与常见观察结果相矛盾的结晶行为。