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基于响应性聚合物刷作为换能器的法布里-珀罗标准具对硫氰酸盐的可视化检测。

Visual Detection of Thiocyanate Based on Fabry-Perot Etalons with a Responsive Polymer Brush as the Transducer.

机构信息

College of Sciences , Northeastern University , Shenyang 110819 , P. R. China.

Chair of Macromolecular Chemistry, School of Science , Technische Universität Dresden , 01069 Dresden , Germany.

出版信息

ACS Sens. 2020 Feb 28;5(2):303-307. doi: 10.1021/acssensors.9b02270. Epub 2020 Feb 12.

Abstract

The detection of thiocyanate (SCN) is particularly important in industrial effluents and biological fluids because of the toxic nature of SCN. Herein, a metal-insulator-metal (MIM) resonator for visual detection of SCN is presented based on a poly[(2-(methacryloyloxy)ethyl) trimethylammonium chloride] (PMETAC) brush. The MIM resonator exhibits obvious color change as the concentration of SCN changes, which can be easily distinguished by the naked eyes. In addition, the as-prepared MIM resonator also shows the advantages of good anti-interference, excellent reusability, and fast response rate. Combining the above advantages, the proposed MIM resonator may provide a broad perspective for a wide variety of visible-light applications.

摘要

硫氰酸盐(SCN)的检测在工业废水中和生物流体中尤为重要,因为 SCN 具有毒性。本文基于聚[(2-(甲基丙烯酰氧)乙基)三甲基氯化铵](PMETAC)刷,提出了一种用于 SCN 可视化检测的金属-绝缘体-金属(MIM)谐振器。随着 SCN 浓度的变化,MIM 谐振器表现出明显的颜色变化,肉眼即可轻松分辨。此外,所制备的 MIM 谐振器还具有良好的抗干扰性、优异的可重复使用性和快速的响应速率等优点。结合以上优点,所提出的 MIM 谐振器可能为各种可见光应用提供广阔的前景。

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