Cui Yinhua, Jeong Jeong Yeul, Gao Yuan, Pyo Sung Gyu
School of Integrative Engineering, Chung-Ang University, Seoul 06974, Korea.
Process Development Center, Magnachip Semiconductor, Seoul 15213, Korea.
Micromachines (Basel). 2020 Feb 6;11(2):170. doi: 10.3390/mi11020170.
Here, we developed the optimal conditions in terms of physical and electrical characteristics of the barrier and tungsten (W) deposition process of a contact module, which is the segment connecting the device and the multi-layer metallization (MLM) metal line in the development of 100 nm-class logic devices. To confirm its applicability to the logic contact of barrier and W films, a contact hole was formed, first to check the bottom coverage and the filling status of each film, then to check the electrical resistance and leakage characteristics to analyze the optimal conditions. At an aspect ratio of 3.89:1, ionized metal plasma (IMP) Ti had a bottom coverage of 40.9% and chemical vapor deposition (CVD) titanium nitride (TiN) of 76.2%, confirming that it was possible to apply the process to 100 nm logic contacts. W filling was confirmed, and a salicide etching rate (using Radio Frequency (RF) etch) of 13-18 Å/s at a 3.53:1 aspect ratio was applied. The etching rate on the thermal oxide plate was 9 Å/s. As the RF etch amount increased from 50-100 Å, the P active resistance increased by 0.5-1 Ω. The resistance also increased as the amount of IMP Ti deposition increased to 300 Å. A measurement of the borderless contact junction leakage current indicated that the current in the P + N well increased by more than an order of magnitude when IMP Ti 250 Å or more was deposited. The contact resistance value was 0.5 Ω. An AC bias improved the IMP Ti deposition rate by 10% in bottom coverage, but there was no significant difference in contact resistance. In the case of applying IMP TiN, the overall contact resistance decreased to 2 Ω compared to CVD TiN, but the distribution characteristics were poor. The best results were obtained under the conditions of RF etch 50 Å, IMP Ti 200 Å, and CVD TiN 2 × 50 Å.
在此,我们针对100纳米级逻辑器件开发过程中连接器件与多层金属化(MLM)金属线的接触模块的势垒以及钨(W)沉积工艺,从物理和电学特性方面制定了最佳条件。为确认其对势垒和W膜逻辑接触的适用性,首先形成一个接触孔,以检查各膜的底部覆盖率和填充状态,然后检查电阻和漏电特性,以分析最佳条件。在纵横比为3.89:1时,电离金属等离子体(IMP)Ti的底部覆盖率为40.9%,化学气相沉积(CVD)氮化钛(TiN)的底部覆盖率为76.2%,这证实了该工艺可应用于100纳米逻辑接触。确认了W填充情况,并在纵横比为3.53:1时采用了13 - 18 Å/s的自对准硅化物蚀刻速率(使用射频(RF)蚀刻)。在热氧化板上的蚀刻速率为9 Å/s。随着RF蚀刻量从50 - 100 Å增加,P有源电阻增加了0.5 - 1 Ω。随着IMP Ti沉积量增加到300 Å,电阻也增加。对无边界接触结泄漏电流的测量表明,当沉积IMP Ti 250 Å或更多时,P + N阱中的电流增加了一个多数量级。接触电阻值为0.5 Ω。交流偏压使IMP Ti沉积速率在底部覆盖率方面提高了10%,但接触电阻没有显著差异。在应用IMP TiN的情况下,与CVD TiN相比,整体接触电阻降至2 Ω,但分布特性较差。在RF蚀刻50 Å、IMP Ti 200 Å和CVD TiN 2×50 Å的条件下获得了最佳结果。