Institute for the Protection of Cultural Heritage of Slovenia, Slovenia.
Pulp and Paper Institute of Ljubljana, Slovenia.
Ultrason Sonochem. 2020 Jun;64:105002. doi: 10.1016/j.ultsonch.2020.105002. Epub 2020 Feb 4.
In paper production industry, microbial contaminations of process waters are common and can cause damage to paper products and equipment as well as the occurrence of pathogens in the end products. Chlorine omission has led to the usage of costly reagents and products of lower mechanical quality. In this study, we have tested a rotation generator equipped with two sets of rotor and stator assemblies to generate developed cavitation (unsteady cloud shedding with pressure pulsations) or supercavitation (a steady cavity in chocked cavitation conditions) for the destruction of a persistent bacteria Bacillus subtilis. Our results showed that only supercavitation was effective and was further employed for the treatment of waters isolated from an enclosed water recycle system in a paper producing plant. The water quality was monitored and assessed according to the chemical (COD, redox potential and dissolved oxygen), physical (settleable solids, insolubles and colour intensity) and biological methods (yeasts, aerobic and anaerobic bacteria, bacterial spores and moulds). After one hour of treatment, a strong 4 logs reduction was achieved for the anaerobic sulphate reducing bacteria and for the yeasts; a 3 logs reduction for the aerobic bacteria; and a 1.3 logs reduction for the heat resistant bacterial spores. A 22% reduction in COD and an increase in the redox potential (37%) were observed. Sediments were reduced by 50% and the insoluble particles by 67%. For bacterial destruction in real industrial process waters, the rotation generator of supercavitation spent 4 times less electrical energy in comparison to the previously published cavitation treatments inside the Venturi constriction design.
在造纸工业中,工艺用水中的微生物污染很常见,可能会损坏纸制品和设备,并导致最终产品中出现病原体。由于氯的缺失,导致使用了昂贵的试剂和机械质量较低的产品。在这项研究中,我们测试了一种配备两组转子和定子组件的旋转发生器,以产生发展性空化(带有压力脉动的不稳定云状脱落)或超空化(阻塞空化条件下的稳定空腔),从而破坏持久细菌枯草芽孢杆菌。我们的结果表明,只有超空化才有效,并进一步将其用于处理从造纸厂封闭水循环系统中分离出来的水。根据化学(COD、氧化还原电位和溶解氧)、物理(可沉降固体、不溶性物质和颜色强度)和生物方法(酵母、需氧和厌氧细菌、细菌孢子和霉菌)监测和评估水质。经过一个小时的处理,厌氧硫酸盐还原菌和酵母的减少量达到了 4 个对数级;需氧细菌减少了 3 个对数级;耐热细菌孢子减少了 1.3 个对数级。COD 减少了 22%,氧化还原电位增加了 37%。沉淀物减少了 50%,不溶性颗粒减少了 67%。对于实际工业过程水中的细菌破坏,与文丘里收缩设计中以前公布的空化处理相比,超空化旋转发生器的电能消耗减少了 4 倍。