通过中离子卡宾钴配合物的卤化物调制来调节电子结构。
Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes.
作者信息
Mantanona Alex J, Tolentino Daniel R, Cay Kristine S, Gembicky Milan, Jazzar Rodolphe, Bertrand Guy, Rinehart Jeffrey D
机构信息
Department of Chemistry and Biochemistry, University of California - San Diego, La Jolla, CA 92093, USA.
出版信息
Dalton Trans. 2020 Feb 25;49(8):2426-2430. doi: 10.1039/c9dt04624k.
The first examples of Co(ii) mesoionic carbene complexes (CoX2DippMIC2; X = Cl-, Br-, I-) demonstrate a new electronic perturbation on tetrahedral Co(ii) complexes. Using absorption spectroscopy and magnetometry, the consequences of the MIC's strong σ-donating/minimal π-accepting nature are analyzed and shown to be further tunable by the nature of the coordinated halide.
首例钴（II）中离子卡宾配合物（CoX2DippMIC2；X = Cl-、Br-、I-）展示了对四面体钴（II）配合物的一种新的电子扰动。利用吸收光谱法和磁强计，分析了中离子卡宾（MIC）强σ供体/最小π受体性质的影响，并表明其可通过配位卤化物的性质进一步调节。
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