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用于钠离子全电池的定制聚酰亚胺作为正极,聚酰亚胺衍生碳作为负极。

Tailored polyimide as positive electrode and polyimide-derived carbon as negative electrode for sodium ion full batteries.

作者信息

Wang Cunguo, Chu Rongrong, Guan Zhixing, Ullah Zaka, Song Hewei, Zhang Yingfei, Yu Congcong, Zhao Liyi, Li Qi, Liu Liwei

机构信息

Key Laboratory of Rubber-Plastics, Ministry of Education; Shandong Province Key Laboratory of Rubber-plastics, Qingdao University of Science and Technology, Qingdao, 266042, China.

Key Laboratory of Nanodevices and Applications & Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS), Suzhou, 215123, China.

出版信息

Nanoscale. 2020 Feb 20;12(7):4729-4735. doi: 10.1039/c9nr09237d.

DOI:10.1039/c9nr09237d
PMID:32049081
Abstract

Organic electrode materials have secured a distinctive place among the auspicious choices for modern energy storage systems due to their resource sustainability and environmental friendliness. Herein, a novel all-organic electrode-based sodium ion full battery is demonstrated using 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTCDA) as raw material for the assembly of positive and negative electrodes. Both the electrodes exhibit excellent cycling stability and rate performance. The fabricated organic sodium ion full battery not only displays a high initial capacity of 157 mA h g-1 with an average battery voltage of 1.47 V under the current density of 100 mA g-1, but also delivers a high energy density of 254 W h kg-1 and a high power density of 614 W kg-1. These sodium ion batteries with organic positive and negative electrode materials can provide a new way for energy storage devices.

摘要

有机电极材料因其资源可持续性和环境友好性,在现代储能系统的众多理想选择中占据了独特地位。在此,展示了一种新型的全有机电极钠离子全电池,它使用1,4,5,8-萘四甲酸二酐(NTCDA)作为组装正负极的原材料。两个电极均表现出优异的循环稳定性和倍率性能。所制备的有机钠离子全电池不仅在100 mA g-1的电流密度下显示出157 mA h g-1的高初始容量,平均电池电压为1.47 V,而且还具有254 W h kg-1的高能量密度和614 W kg-1的高功率密度。这些具有有机正负极材料的钠离子电池可为储能装置提供一种新途径。

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