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温度对 Kolliphor ELP 水溶液吸附和体积性质的影响。

Temperature Effect on the Adsorption and Volumetric Properties of Aqueous Solutions of KolliphorELP.

机构信息

Department of Interfacial Phenomena, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University in Lublin, Maria Curie-Skłodowska Sq. 3, Lublin 20-031, Poland.

出版信息

Molecules. 2020 Feb 9;25(3):743. doi: 10.3390/molecules25030743.

DOI:10.3390/molecules25030743
PMID:32050404
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7037185/
Abstract

Density, viscosity and surface tension of Kolliphor ELP, the nonionic surfactant aqueous solutions were measured at temperature T = 293-318 K and at 5K interval. Steady-state fluorescence measurements have been also made using pyrene as a probe. On the basis of the obtained results, a number of thermodynamic, thermo-acoustic and anharmonic parameters of the studied surfactant have been evaluated and interpreted in terms of structural effects and solute-solvent interactions. The results suggest that the molecules of studied surfactant at concentrations higher than the critical micelle concentration act as structure makers of the water structure.

摘要

在温度 T = 293-318 K 范围内,以 5K 的间隔测量了非离子表面活性剂 kolliphor elp 的密度、粘度和表面张力水溶液。还使用芘作为探针进行了稳态荧光测量。基于获得的结果,评估并解释了研究表面活性剂的许多热力学、热声和非谐参数,以结构效应和溶质-溶剂相互作用。结果表明,在高于临界胶束浓度的浓度下,研究表面活性剂的分子充当水结构的结构形成剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/e9c78195e7cc/molecules-25-00743-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/dd73ce6f2bb0/molecules-25-00743-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/e5d0e2c1d1b3/molecules-25-00743-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/25aadef026b1/molecules-25-00743-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/02aa85882ca0/molecules-25-00743-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/f939dce1231e/molecules-25-00743-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/b27cc054cf0d/molecules-25-00743-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/be9e2e1173ce/molecules-25-00743-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/477348b12421/molecules-25-00743-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/f98ff5a3f2ee/molecules-25-00743-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/1b10780a942f/molecules-25-00743-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/113be05bff42/molecules-25-00743-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/e9c78195e7cc/molecules-25-00743-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/dd73ce6f2bb0/molecules-25-00743-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/e5d0e2c1d1b3/molecules-25-00743-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/25aadef026b1/molecules-25-00743-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/02aa85882ca0/molecules-25-00743-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/f939dce1231e/molecules-25-00743-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/b27cc054cf0d/molecules-25-00743-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/be9e2e1173ce/molecules-25-00743-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/477348b12421/molecules-25-00743-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/f98ff5a3f2ee/molecules-25-00743-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/1b10780a942f/molecules-25-00743-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/113be05bff42/molecules-25-00743-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cc/7037185/e9c78195e7cc/molecules-25-00743-g012.jpg

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