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用于增强柔性锂离子微型电池循环性能的电聚合碳纳米管直接预锂化

Direct Pre-lithiation of Electropolymerized Carbon Nanotubes for Enhanced Cycling Performance of Flexible Li-Ion Micro-Batteries.

作者信息

Sugiawati Vinsensia Ade, Vacandio Florence, Yitzhack Neta, Ein-Eli Yair, Djenizian Thierry

机构信息

Mines Saint-Etienne, Center of Microelectronics in Provence, Department of Flexible Electronics, F-13541 Gardanne, France.

CNRS, Electrochemistry of Materials Research Group, Aix Marseille Université, MADIREL, UMR 7246, F-13397 Marseille CEDEX 20, France.

出版信息

Polymers (Basel). 2020 Feb 11;12(2):406. doi: 10.3390/polym12020406.

DOI:10.3390/polym12020406
PMID:32054002
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7077669/
Abstract

Carbon nanotubes (CNT) are used as anodes for flexible Li-ion micro-batteries. However, one of the major challenges in the growth of flexible micro-batteries with CNT as the anode is their immense capacity loss and a very low initial coulombic efficiency. In this study, we report the use of a facile direct pre-lithiation to suppress high irreversible capacity of the CNT electrodes in the first cycles. Pre-lithiated polymer-coated CNT anodes displayed good rate capabilities, studied up to 30 C and delivered high capacities of 850 mAh g (313 μAh cm) at 1 C rate over 50 charge-discharge cycles.

摘要

碳纳米管（CNT）被用作柔性锂离子微型电池的阳极。然而，以碳纳米管作为阳极来生长柔性微型电池面临的主要挑战之一是其巨大的容量损失以及非常低的初始库仑效率。在本研究中，我们报告了使用一种简便的直接预锂化方法来抑制碳纳米管电极在首个循环中的高不可逆容量。预锂化的聚合物包覆碳纳米管阳极展现出良好的倍率性能，在高达30 C的倍率下进行了研究，并在1 C倍率下经过50次充放电循环后提供了850 mAh g（313 μAh cm）的高容量。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/775967165259/polymers-12-00406-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/77f0a62ff6e5/polymers-12-00406-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/08fdc7ab8a7a/polymers-12-00406-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/275f018123d9/polymers-12-00406-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/d74451e9d053/polymers-12-00406-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/bdd302865cd4/polymers-12-00406-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/dd8a50a6f17b/polymers-12-00406-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/c23d32b3e2e5/polymers-12-00406-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/775967165259/polymers-12-00406-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/77f0a62ff6e5/polymers-12-00406-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/08fdc7ab8a7a/polymers-12-00406-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/275f018123d9/polymers-12-00406-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/d74451e9d053/polymers-12-00406-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/bdd302865cd4/polymers-12-00406-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/dd8a50a6f17b/polymers-12-00406-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/c23d32b3e2e5/polymers-12-00406-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d54/7077669/775967165259/polymers-12-00406-g008.jpg

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Small. 2019 Oct;15(42):e1902183. doi: 10.1002/smll.201902183. Epub 2019 Aug 28.
2
Modulating Carrier Type for Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyethyleneimine Composites.调节载流子类型以增强单壁碳纳米管/聚乙烯亚胺复合材料的热电性能
Polymers (Basel). 2019 Aug 2;11(8):1295. doi: 10.3390/polym11081295.
3
Sputtered Porous Li-Fe-P-O Film Cathodes Prepared by Radio Frequency Sputtering for Li-ion Microbatteries.
双层石墨烯与单壁纳米管在轴向拉伸下形成的混合薄膜的导电和电化学性质的计算机模拟研究。
Membranes (Basel). 2021 Aug 26;11(9):658. doi: 10.3390/membranes11090658.
4
High Electrochemical Performance Silicon Thin-Film Free-Standing Electrodes Based on Buckypaper for Flexible Lithium-Ion Batteries.基于巴基纸的用于柔性锂离子电池的高电化学性能硅薄膜独立电极
Materials (Basel). 2021 Apr 19;14(8):2053. doi: 10.3390/ma14082053.
5
All-Solid-State Lithium Ion Batteries Using Self-Organized TiO Nanotubes Grown from Ti-6Al-4V Alloy.使用自组织 TiO 纳米管的全固态锂离子电池，该纳米管由 Ti-6Al-4V 合金生长而成。
Molecules. 2020 May 1;25(9):2121. doi: 10.3390/molecules25092121.
6
Carbon-Based Polymer Nanocomposites for High-Performance Applications.用于高性能应用的碳基聚合物纳米复合材料。
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4
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8
Dry-air-stable lithium silicide-lithium oxide core-shell nanoparticles as high-capacity prelithiation reagents.干燥空气稳定的硅化锂-氧化锂核壳纳米颗粒作为高容量预锂化试剂。
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Nat Commun. 2014 Jul 31;5:4526. doi: 10.1038/ncomms5526.
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ACS Appl Mater Interfaces. 2014 Mar 12;6(5):3290-8. doi: 10.1021/am405197s. Epub 2014 Feb 20.