Zhu Lin, Tian Xiaolong, Pan Yiren, Chang Tianhao, Wang Kongshuo, Niu Guangzhi, Zhang Luqi, Wang Chuansheng, Han Wenwen
College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China.
Shandong Provincial Key Laboratory of Polymer Material Advanced Manufacturing Technology, Qingdao University of Science and Technology, Qingdao 266061, China.
Polymers (Basel). 2020 Feb 11;12(2):416. doi: 10.3390/polym12020416.
In the tire industry, the combination of carbon black and silica is commonly utilized to improve the comprehensive performance of natural rubber so as to realize the best performance and cost-effectiveness. The corresponding mixing is divided into three processes (initial mixing, delivery, reactive mixing) by the serial modular continuous mixing method, thus achieving more accurate control of the mixing process, higher production efficiency and better performance. Moreover, the optimization of serial modular continuous mixing process parameters can not only improve the performance of composite materials, but help people understand the physical and chemical changes and the reinforcing mechanism of fillers in the mixing process. In this paper, the relationship among the parameters of eight processes and filler network structure, tensile strength, chemical reinforcing effect and tear resistance was explored through experiments. The deep causes of performance changes caused by parameters were analyzed. Consequently, the best process condition and the ranking of the influencing factors for a certain performance was obtained. Furthermore, the best preparation process of natural rubber (NR)/carbon black/silica composite was achieved through comprehensive analysis.
在轮胎工业中,炭黑与白炭黑的组合通常用于改善天然橡胶的综合性能,以实现最佳性能和成本效益。相应的混合过程采用串联模块化连续混合方法分为三个过程(初始混合、输送、反应性混合),从而实现对混合过程更精确的控制、更高的生产效率和更好的性能。此外,串联模块化连续混合工艺参数的优化不仅可以提高复合材料的性能,还有助于人们了解混合过程中填料的物理和化学变化以及增强机理。本文通过实验探究了八个过程的参数与填料网络结构、拉伸强度、化学增强效果和抗撕裂性之间的关系。分析了参数引起性能变化的深层原因。从而获得了最佳工艺条件和某一性能的影响因素排名。此外,通过综合分析得出了天然橡胶(NR)/炭黑/白炭黑复合材料的最佳制备工艺。