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锌空气电池:它们准备好迎接黄金时代了吗?

Zinc-air batteries: are they ready for prime time?

作者信息

Zhang Jie, Zhou Qixing, Tang Yawen, Zhang Liang, Li Yanguang

机构信息

Institute of Functional Nano and Soft Materials (FUNSOM) , Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices , Soochow University , Suzhou 215123 , China . Email:

Jiangsu Key Laboratory of New Power Batteries , Jiangsu Collaborative Innovation Center of Biomedical Functional Materials , School of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , China.

出版信息

Chem Sci. 2019 Sep 24;10(39):8924-8929. doi: 10.1039/c9sc04221k. eCollection 2019 Oct 21.

Abstract

Zn-air batteries are under revival. They have large theoretical energy density and potentially very low manufacturing cost compared to the existing Li-ion technology. However, their full potential has not been fulfilled due to challenges associated with air cathodes and Zn anodes. In this minireview, we present the current status and technical hurdles of Zn-air batteries and discuss the possible direction of their future improvements. We show that in contrast to tremendous efforts on the design and development of efficient cathode electrocatalysts over recent years, the pursuit of stable and cyclable Zn anodes is equally important but receives far less attention than deserved. We therefore call for a shift of future research focus from cathode electrocatalysts to Zn anodes in order to make this century old technology a truly commercial reality.

摘要

锌空气电池正在复兴。与现有的锂离子技术相比,它们具有较大的理论能量密度,并且潜在制造成本极低。然而,由于与空气阴极和锌阳极相关的挑战,它们的全部潜力尚未得到实现。在这篇微型综述中,我们介绍了锌空气电池的现状和技术障碍,并讨论了其未来改进的可能方向。我们表明,与近年来在高效阴极电催化剂的设计和开发上付出的巨大努力形成对比的是,追求稳定且可循环的锌阳极同样重要,但却远未得到应有的关注。因此,我们呼吁未来的研究重点从阴极电催化剂转向锌阳极,以使这项有着百年历史的技术真正实现商业化。

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