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冲压对Mg-2Zn-0.5Nd(ZN20)板材生物降解行为的影响。

Influence of stamping on the biodegradation behavior of Mg-2Zn-0.5Nd (ZN20) sheet.

作者信息

Etim Iniobong P, Zhang Wen, Tan Lili, Yang Ke

机构信息

Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China.

School of Materials Science and Engineering, University of Science and Technology of China, Shenyang, 110016, China.

出版信息

Bioact Mater. 2020 Feb 5;5(1):133-141. doi: 10.1016/j.bioactmat.2020.01.009. eCollection 2020 Mar.

Abstract

Stamping processing is commonly used to form medical devices and implant. However, for biodegradable Mg alloy, the stamping will influence the degradation behavior because of the change in microstructure after stamping. So in this study, the As-rolled Mg-2Zn-0.5Nd alloy (ZN20) was processed by stamping. The microstructure, crystallographic orientation and corrosion performance of this processing method was investigated to reveal the influence of the stamping process on the degradation rate of Rolled Mg-2Zn-Nd (ZN20). The degradation rate was measured by immersion of the Mg-2Zn-0.5Nd alloy in simulated body fluid using Electrochemical Impedance Spectroscopy, Potentiodynamic polarization and mass loss. The in vitro degradation result shows that the degradation rate of the Rolled Mg-2Zn-0.5Nd increased from 0.2 mm/year to 0.5 mm/year after stamping processing. The result reveals that the activation of the tension twin during stamping can remarkably weaken the 0001} basal texture and have a significant influence on the corrosion rate of Stamped Mg-2Zn-0.5Nd sheet. After removing the deformation by annealing, the degradation rate was reduced to 0.15 mm/year. This work is expected to prompt better microstructural design of biomedical Mg in order to control its degradation behavior for biomedical application.

摘要

冲压加工常用于制造医疗器械和植入物。然而,对于可生物降解的镁合金,冲压会影响其降解行为,因为冲压后微观结构会发生变化。因此,在本研究中,对轧制态Mg-2Zn-0.5Nd合金(ZN20)进行了冲压加工。研究了这种加工方法的微观结构、晶体取向和腐蚀性能,以揭示冲压工艺对轧制态Mg-2Zn-Nd(ZN20)降解速率的影响。通过将Mg-2Zn-0.5Nd合金浸泡在模拟体液中,采用电化学阻抗谱、动电位极化和质量损失法来测量降解速率。体外降解结果表明,轧制态Mg-2Zn-0.5Nd冲压加工后的降解速率从0.2毫米/年增加到0.5毫米/年。结果表明,冲压过程中拉伸孪晶的激活可显著弱化{0001}基面织构,并对冲压态Mg-2Zn-0.5Nd板材的腐蚀速率产生重大影响。退火消除变形后,降解速率降至0.15毫米/年。这项工作有望促进生物医用镁更好的微观结构设计,以便控制其在生物医学应用中的降解行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c9e/7005560/3be45e7afc88/fx1.jpg

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