Liu Ya, Wen Jiuba, Yao Huai, He Junguang, Li Huan
School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China.
Collaborative Innovation Center of Nonferrous Metals of Henan Province, Luoyang 471023, China.
Materials (Basel). 2020 Feb 12;13(4):836. doi: 10.3390/ma13040836.
Microstructure and corrosion behavior of the solution-treated Mg-1.8Zn-1.74Gd-0.5Y-0.4Zr (wt%) alloy were studied. The results of microstructure indicated that the second phases of as-cast alloy was mainly comprised of MgZn(Gd,Y) phase, MgZn(Gd,Y) phase and (Mg,Zn)(Gd,Y) phase. After solution treatment process, the second phase gradually dissolved into the matrix, and the grain size increased. The effect of microgalvanic corrosion between α-Mg matrix and second phase was also improved. At the range of 470~510 °C solution treatment temperature, the corrosion resistance of the samples increases at first and then decreases slightly at 510 °C. All the solution-treated Mg-Zn-Gd-Y-Zr samples exhibit better corrosion resistance in comparison with as-cast sample. The existence form of the remaining phase affects the morphology of the corroded surface that relatively complete dissolution with homogeneous microstructure makes the sample more effective to obtain uniform corrosion form. The optimum temperature for solution treatment is 490 °C, which shows a much better corrosion resistance and uniform corrosion form after soaking for a long time.
研究了固溶处理后的Mg-1.8Zn-1.74Gd-0.5Y-0.4Zr(wt%)合金的微观结构和腐蚀行为。微观结构研究结果表明,铸态合金的第二相主要由MgZn(Gd,Y)相、MgZn(Gd,Y)相和(Mg,Zn)(Gd,Y)相组成。经过固溶处理后,第二相逐渐溶解到基体中,晶粒尺寸增大。α-Mg基体与第二相之间的微电偶腐蚀效应也得到改善。在470~510℃固溶处理温度范围内,样品的耐蚀性先升高,在510℃时略有下降。与铸态样品相比,所有固溶处理后的Mg-Zn-Gd-Y-Zr样品均表现出更好的耐蚀性。残余相的存在形式影响腐蚀表面的形貌,相对完全溶解且微观结构均匀使样品更易获得均匀腐蚀形式。固溶处理的最佳温度为490℃,长时间浸泡后表现出更好的耐蚀性和均匀腐蚀形式。