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PFAS 污染土壤新兴处理技术综述。

A review of the emerging treatment technologies for PFAS contaminated soils.

机构信息

School of Engineering, Faculty of Business, Justice and Behavioural Sciences, Charles Sturt University, New South Wales, Australia.

出版信息

J Environ Manage. 2020 Feb 1;255:109896. doi: 10.1016/j.jenvman.2019.109896. Epub 2019 Dec 26.

Abstract

Contamination of soils with poly- and perfluoroalkyl substances (PFAS) has become a challenging issue due to the adverse effects of these substances on both the environment and public health. PFAS have strong chemical structures and their bonding with soil makes them challenging to eliminate from soil environments. Traditional methods of soil remediation have not been successful in their reduction or removal from the environment. This paper provides a comprehensive evaluation of existing and emerging technologies for remediating PFAS contaminated soils with guidance on which approach to use in different contexts. The functions of all remediation technologies, their suitability, limitations, and the scale applied from laboratory to the field are presented as a baseline for understanding the research need for treatment in soil environments. To date, the immobilization method has been a significant part of the remediation solution for PFAS contaminated soils, although its long-term efficiency still needs further investigation. Soil washing and thermal treatment techniques have been tested at the field scale, but they are expensive and energy-intensive due to the use of a large volume of washing solvent and the high melting point of PFAS, respectively; both methods need a large initial investment for their installation. Other remediation technologies, such as chemical oxidation, ball milling, and electron beams, have been progressed in the laboratory. However, additional research is needed to make them feasible, cost-effective and applicable in the field.

摘要

由于这些物质对环境和公众健康的不利影响,土壤中多氟和全氟烷基物质(PFAS)的污染已成为一个具有挑战性的问题。PFAS 具有很强的化学结构,它们与土壤的结合使得它们难以从土壤环境中消除。传统的土壤修复方法在减少或去除这些物质方面并不成功。本文对现有的和新兴的修复 PFAS 污染土壤的技术进行了全面评估,并就不同情况下应采用哪种方法提供了指导。本文介绍了所有修复技术的功能、适用性、局限性以及从实验室到现场应用的规模,为了解在土壤环境中进行处理的研究需求提供了一个基准。迄今为止,固定化方法一直是 PFAS 污染土壤修复解决方案的重要组成部分,尽管其长期效率仍需要进一步研究。尽管土壤洗涤和热处理技术已在现场规模进行了测试,但由于使用了大量的洗涤溶剂以及 PFAS 的高熔点,这两种方法都很昂贵且能源密集型;这两种方法都需要大量的初始投资来安装。其他修复技术,如化学氧化、球磨和电子束,已在实验室中取得进展。然而,需要进一步的研究使它们在现场可行、具有成本效益和适用。

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