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使用受限撞击射流混合器制备具有不同分散相含量的水包油乳液。

Production of Oil-in-Water Emulsions with Varying Dispersed-Phase Content using Confined Impinging Jet Mixers.

作者信息

Tripodi Ernesto, Lazidis Aristodimos, Norton Ian T, Spyropoulos Fotis

机构信息

School of Chemical Engineering, University of Birmingham, B15 2TT Birmingham, United Kingdom.

出版信息

Ind Eng Chem Res. 2019 Aug 14;58(32):14859-14872. doi: 10.1021/acs.iecr.9b00634. Epub 2019 Jul 8.

Abstract

This work reports for the first time on the use of Confined Impinging Jet Mixers (CIJM) for the production of emulsions with dispersed-phase content up to 80 wt %, in both the surfactant-poor and -rich regimes, following the exposure to varying CIJM hydrodynamic conditions. It was observed computationally and experimentally that the CIJM capacity resulted strictly dependent on the mass jet flow rate ( > 176 g/min) and the pre-emulsion droplet size (>10 μm). CIJM emulsification performance remained (almost) unaffected by the variation in the oil mass fraction. All systems showed the lowest droplet size (∼8 μm) and similar droplet size distributions under the highest . Conditionally onto the Tween20 availability, the emulsion was primarily determined by formulation characteristics in the surfactant poor-regime and by the CIJM energy dissipation rate in the surfactant-rich regime. In conclusion, this study offers further insights into the CIJM suitability as a realistic alternative to already-established emulsification methods.

摘要

这项工作首次报道了在暴露于不同的受限冲击射流混合器(CIJM)流体动力学条件下,在贫表面活性剂和富表面活性剂体系中使用CIJM制备分散相含量高达80 wt%的乳液。通过计算和实验观察到,CIJM的能力严格取决于质量射流流速(>176 g/min)和预乳液液滴尺寸(>10 μm)。CIJM的乳化性能几乎不受油相质量分数变化的影响。在最高[具体条件未明确]下,所有体系均显示出最低的液滴尺寸(约8 μm)和相似的液滴尺寸分布。在吐温20存在的条件下,乳液[具体情况未明确]主要由贫表面活性剂体系中的配方特性和富表面活性剂体系中的CIJM能量耗散率决定。总之,本研究进一步深入了解了CIJM作为现有乳化方法的一种切实可行替代方法的适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a9c/7011702/951cf4e66113/ie9b00634_0001.jpg

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