Tripodi Ernesto, Lazidis Aristodimos, Norton Ian T, Spyropoulos Fotis
School of Chemical Engineering, University of Birmingham, B15 2TT Birmingham, United Kingdom.
Ind Eng Chem Res. 2019 Aug 14;58(32):14859-14872. doi: 10.1021/acs.iecr.9b00634. Epub 2019 Jul 8.
This work reports for the first time on the use of Confined Impinging Jet Mixers (CIJM) for the production of emulsions with dispersed-phase content up to 80 wt %, in both the surfactant-poor and -rich regimes, following the exposure to varying CIJM hydrodynamic conditions. It was observed computationally and experimentally that the CIJM capacity resulted strictly dependent on the mass jet flow rate ( > 176 g/min) and the pre-emulsion droplet size (>10 μm). CIJM emulsification performance remained (almost) unaffected by the variation in the oil mass fraction. All systems showed the lowest droplet size (∼8 μm) and similar droplet size distributions under the highest . Conditionally onto the Tween20 availability, the emulsion was primarily determined by formulation characteristics in the surfactant poor-regime and by the CIJM energy dissipation rate in the surfactant-rich regime. In conclusion, this study offers further insights into the CIJM suitability as a realistic alternative to already-established emulsification methods.
这项工作首次报道了在暴露于不同的受限冲击射流混合器(CIJM)流体动力学条件下,在贫表面活性剂和富表面活性剂体系中使用CIJM制备分散相含量高达80 wt%的乳液。通过计算和实验观察到,CIJM的能力严格取决于质量射流流速(>176 g/min)和预乳液液滴尺寸(>10 μm)。CIJM的乳化性能几乎不受油相质量分数变化的影响。在最高[具体条件未明确]下,所有体系均显示出最低的液滴尺寸(约8 μm)和相似的液滴尺寸分布。在吐温20存在的条件下,乳液[具体情况未明确]主要由贫表面活性剂体系中的配方特性和富表面活性剂体系中的CIJM能量耗散率决定。总之,本研究进一步深入了解了CIJM作为现有乳化方法的一种切实可行替代方法的适用性。