Gao Jia, Geng Shubo, Chen Yao, Cheng Peng, Zhang Zhenjie
College of Chemistry, Nankai University, Tianjin, 300071, China.
College of Pharmacy, Nankai University, Tianjin, 300071, China.
Top Curr Chem (Cham). 2020 Feb 18;378(2):25. doi: 10.1007/s41061-020-0288-6.
Two-dimensional (2D) metal-organic frameworks (MOFs) belong to a subgroup of MOFs reminiscent of graphite and covalent organic frameworks (COFs). In the past decade, conductive 2D MOFs have received increasing attention due to their relatively high charge carrier mobility and low resistivity that originate from in-plane charge delocalization and extended π conjugation within the layers. This review comprises the current state-of-the-art of the representative progress in theoretical exploration and electronic applications of conductive 2D MOFs. Special emphasis is placed on the intrinsic relations between the structural factors and the electronic properties of conductive 2D MOFs. This review will provide guidance for researchers to design and synthesize conductive 2D MOFs for advanced applications.
二维（2D）金属有机框架（MOF）属于MOF的一个子群，类似于石墨和共价有机框架（COF）。在过去十年中，导电二维MOF因其相对较高的载流子迁移率和低电阻率而受到越来越多的关注，这些特性源于平面内电荷离域和层内扩展的π共轭。本综述涵盖了导电二维MOF在理论探索和电子应用方面的代表性进展的当前最新情况。特别强调了导电二维MOF的结构因素与电子性质之间的内在关系。本综述将为研究人员设计和合成用于先进应用的导电二维MOF提供指导。
