Zhang Zhaohui, Wu Chenyu, Pan Qingyan, Shao Feng, Sun Qingzhu, Chen Siqi, Li Zhibo, Zhao Yingjie
College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
Chem Commun (Camb). 2020 Mar 12;56(21):3210-3213. doi: 10.1039/c9cc09617e.
A well-defined crystalline cyano-functionalized graphdiyne (CN-GDY) is synthesized at a liquid/liquid interface through alkyne-alkyne coupling reactions. The configurations and nanostructures of CN-GDY were well characterized by TEM, SEM, AFM, XPS, and Raman spectroscopy. HR-TEM and selected area electron diffraction (SAED) in combination with structure simulation firmly revealed a 9-fold stacking mode for CN-GDY.
通过炔-炔偶联反应在液/液界面合成了一种结构明确的结晶氰基功能化石墨二炔（CN-GDY）。通过透射电子显微镜（TEM）、扫描电子显微镜（SEM）、原子力显微镜（AFM）、X射线光电子能谱（XPS）和拉曼光谱对CN-GDY的构型和纳米结构进行了充分表征。高分辨透射电子显微镜（HR-TEM）和选区电子衍射（SAED）结合结构模拟，确凿地揭示了CN-GDY的九重堆积模式。
