二合一：一锅法构建羟基和咪唑鎓双功能化离子网络用于协同催化CO固定
Two-in-one: construction of hydroxyl and imidazolium-bifunctionalized ionic networks in one-pot toward synergistic catalytic CO fixation.
作者信息
Zhang Yadong, Chen Guojian, Wu Lei, Liu Ke, Zhong Hu, Long Zhouyang, Tong Minman, Yang Zhenzhen, Dai Sheng
机构信息
School of Chemistry and Materials Science, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, 221116, China.
Department of Chemistry, The University of Tennessee, Knoxville, TN 37996, USA and Chemical Sciences Division, Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831, USA.
出版信息
Chem Commun (Camb). 2020 Mar 17;56(22):3309-3312. doi: 10.1039/c9cc09643d.
A succinct strategy was demonstrated for constructing a hydroxyl group and imidazolium-bifunctionalized ionic network via a one-pot quaternization. Key to success lies in the rational design of multi-imidazole precursor and hydroxyl-containing counterpart. Unique properties of the resultant ionic network render its high catalytic efficiency toward CO2 fixation under ambient conditions.
展示了一种简洁的策略，通过一锅法季铵化构建羟基和咪唑鎓双功能化离子网络。成功的关键在于多咪唑前体和含羟基对应物的合理设计。所得离子网络的独特性质使其在环境条件下对二氧化碳固定具有高催化效率。
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