通过光诱导自由基硫醇-烯加成（TEC）法无金属合成亚氨基二糖和杯[4]亚氨基糖。
Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol-ene coupling (TEC).
机构信息
Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS, Université de Montpellier, Ecole Nationale Supérieure de Chimie de Montpellier, 8 Rue de l'Ecole Normale, 34296 Montpellier cedex 5, France.
出版信息
Org Biomol Chem. 2020 Apr 1;18(13):2392-2397. doi: 10.1039/d0ob00198h.
PMID:32083269
Abstract
Radical thiol-ene coupling was exploited for the first time to prepare imino-disaccharides and multivalent iminosugars starting from sugar thiols and iminosugar alkenes or iminosugar thiols and tetra-allylated calixarene, respectively.
摘要
首次利用自由基硫醇-烯偶联反应，分别以糖硫醇和亚胺糖烯烃或亚胺糖硫醇和四烯丙基杯[4]芳烃为起始原料，制备了亚氨基二糖和多价亚氨基糖。
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