Highly Efficient Catalysts of Bimetallic Pt-Ru Nanocrystals Supported on Ordered ZrO Nanotube for Toluene Oxidation.

ZrO nanotube arrays and their supported bimetallic platinum and ruthenium (PtRu/ZrO; + = 1 mmol %, / = 1:0, 0.9:0.1, 0.8:0.2, 0.7:0.3, 0.5:0.5, 0:1) nanocomposites were fabricated by employing SBA-15-OH as a hard template and an impregnation method, respectively. A controlled ordered nanotube array structure formed from the fabricated catalysts, and it showed a good performance for toluene oxidation. The specific physicochemical properties of the catalysts were examined through various analytical means. The PtRu/ZrO possessed a high surface area, and the Pt-Ru nanoparticles were dispersed uniformly on the ZrO nanotube surface. The PtRu/ZrO catalyst performed best among all of the samples, with and (temperatures for 90 and 100% conversion of toluene) of 140 and 160 °C, respectively, at a weight hourly space velocity of 36 000 mL/(h·g). These bimetallic catalysts exhibit excellent characteristics for toluene oxidation, such as higher turnover frequencies and lower apparent activation energy () values, which probably result from the synergistic effect of the Pt-Ru noble metals that leads to a high reducibility and oxygen adsorption capacity. The excellent activity, stability, and economics of the PtRu/ZrO catalyst allow for its application in toluene removal.