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特定镧系元素在异常高温下的磁有序:镨呢?

Magnetic ordering at anomalously high temperatures in selected lanthanides: what about Pr?

作者信息

Song Jing, Schilling James S

机构信息

Department of Physics, Washington University, St. Louis, Missouri, 63130, United States of America. Department of Physics, Harvard University, Cambridge, Massachusetts, 02138, United States of America.

出版信息

J Phys Condens Matter. 2020 Jun 10;32(25):254001. doi: 10.1088/1361-648X/ab79f7.

Abstract

Recent experiments have given evidence that for elemental Nd, Tb, and Dy the application of sufficient pressure pushes their magnetic ordering temperatures to anomalously high values. Pr metal has a dhcp structure and is trivalent with the 4f configuration. Its singlet ground state suppresses magnetic order from the 15 K anticipated from de Gennes scaling to 50 mK. Four-point electrical resistivity measurements were carried out on Pr for temperatures 1.5-295 K under pressures to 48 GPa. Although no clear evidence for magnetic order (or superconductivity) is observed above 1.5 K, the temperature dependence of the resistivity gives evidence that Pr may enter a dense Kondo state above 10 GPa.

摘要

最近的实验表明,对于元素钕(Nd)、铽(Tb)和镝(Dy),施加足够的压力会将它们的磁有序温度推至异常高的值。镨(Pr)金属具有双六方密堆积(dhcp)结构,是具有4f构型的三价金属。其单重基态将磁有序从德热纳标度预期的15 K抑制到50 mK。在压力高达48 GPa的条件下,对镨在1.5 - 295 K的温度范围内进行了四点电阻率测量。尽管在1.5 K以上未观察到磁有序(或超导)的明确证据,但电阻率的温度依赖性表明,镨在10 GPa以上可能进入密集的近藤态。

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