Zhang Xingchen, Gao Jianen, Fan Henghui, Li Xinghua, Gao Zhe, Xue Li, Sun Shengli
Institute of Soil and Water Conservation, Chinese Academy of Sciences and Ministry of Water Resources, Yangling 712100, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
Nanomaterials (Basel). 2020 Feb 25;10(3):405. doi: 10.3390/nano10030405.
A new nano-soil stabilizer (N-MBER, Nanometer Material Becoming Earth into Rock) material was developed in this research by using the high activity and ultrafine properties of nano-SiO (NS), which were able to improve the properties of cement-based soil stabilizer and had broad application prospects. The results showed that (1) the strength of N-MBER obeyed a compound function relation with curing period and additive amount of NS. The relationship between strength and curing period obeyed an exponential function when the additive amount was constant. The strength and additive amount were a power function when the curing period was fixed. The compressive strength of N-MBER increased by more than 15% compared with MBER at day 28 of the curing period, and 50% compared with grade 32.5 cement. (2) The pozzolanic catalytic activity of NS significantly increased the amount of calcium silicate hydrate gel (C-S-H) in the N-MBER colloid. NS was also able to make the distribution of the network structure of colloidal space more uniform and improved the fractal dimension of particles by 0.05. The above results provide theoretical data for exploring the mechanism of soil stabilizer strength growth and for promoting the application of solid waste utilization.
本研究利用纳米二氧化硅(NS)的高活性和超细微特性,开发出一种新型纳米土壤稳定剂(N-MBER,纳米材料使土成岩),该材料能够改善水泥基土壤稳定剂的性能,具有广阔的应用前景。结果表明:(1)N-MBER的强度与养护期和NS掺量服从复合函数关系。当掺量恒定时,强度与养护期服从指数函数关系。当养护期固定时,强度与掺量为幂函数关系。在养护期28天时,N-MBER的抗压强度比MBER提高了15%以上,比32.5级水泥提高了50%。(2)NS的火山灰催化活性显著增加了N-MBER胶体中硅酸钙水化物凝胶(C-S-H)的含量。NS还能使胶体空间网络结构分布更均匀,颗粒分形维数提高0.05。上述结果为探索土壤稳定剂强度增长机理及促进固体废弃物利用应用提供了理论数据。