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活化扩散泳

Activated diffusiophoresis.

作者信息

Rohwer Christian M, Kardar Mehran, Krüger Matthias

机构信息

Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, Germany.

Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

出版信息

J Chem Phys. 2020 Feb 28;152(8):084109. doi: 10.1063/1.5139017.

DOI:10.1063/1.5139017
PMID:32113334
Abstract

Perturbations of fluid media can give rise to non-equilibrium dynamics, which may, in turn, cause motion of immersed inclusions or tracer particles. We consider perturbations ("activations") that are local in space and time, of a fluid density which is conserved, and study the resulting diffusiophoretic phenomena that emerge at a large distance. Specifically, we consider cases where the perturbations propagate diffusively, providing examples from passive and active matter for which this is expected to be the case. Activations can, for instance, be realized by sudden and local changes in interaction potentials of the medium or by local changes in its activity. Various analytical results are provided for the case of confinement by two parallel walls. We investigate the possibility of extracting work from inclusions, which are moving through the activated fluid. Furthermore, we show that a time-dependent density profile, created via suitable activation protocols, allows for the conveyance of inclusions along controlled and stable trajectories. In contrast, in states with a steady density, inclusions cannot be held at stable positions, reminiscent of Earnshaw's theorem of electrostatics. We expect these findings to be applicable in a range of experimental systems. The phenomena described here are argued to be distinct from other forms of phoresis such as thermophoresis.

摘要

流体介质的扰动会引发非平衡动力学,进而可能导致浸入其中的内含物或示踪粒子的运动。我们考虑在空间和时间上局部的、关于守恒流体密度的扰动(“激活”),并研究在远距离出现的由此产生的扩散电泳现象。具体而言,我们考虑扰动以扩散方式传播的情况,并从被动物质和活性物质中给出预期会出现这种情况的例子。例如,激活可以通过介质相互作用势的突然局部变化或其活性的局部变化来实现。针对由两个平行壁限制的情况给出了各种分析结果。我们研究了从在激活流体中移动的内含物提取功的可能性。此外,我们表明,通过合适的激活协议创建的随时间变化的密度分布允许内含物沿着受控且稳定的轨迹输送。相比之下,在密度稳定的状态下,内含物无法保持在稳定位置,这让人联想到静电学中的厄恩肖定理。我们预计这些发现将适用于一系列实验系统。这里描述的现象被认为与其他形式的泳动现象(如热泳)不同。

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