Wang Meng-Meng, Zhao Yan-Xia, Ding Xun-Lei, Li Wei, He Sheng-Gui
School of Mathematics and Physics, North China Electric Power University, Beinong Road 2, Huilongguan, Beijing 102206, P. R. China.
Phys Chem Chem Phys. 2020 Mar 21;22(11):6231-6238. doi: 10.1039/c9cp05699h. Epub 2020 Mar 4.
The ability to activate methane differs appreciably for different transition metals, and it is attractive to find the most suitable metal for the direct conversion of methane to value-added chemicals. Herein, we performed a comparative study on the reactions of CH with Au, AuRh and Rh cations by mass-spectrometry based experiments and DFT-based theoretical analysis. Different reactivity has been found for these cations: Au has the lowest reactivity, and it can activate methane but only produce H-Au-CH without H release; Rh has the highest reactivity, and it can produce both carbene-type Rh-CH and carbyne-type H-Rh-CH with H release; AuRh also has high reactivity to produce only AuRh-CH with H, avoiding the excessive dehydrogenation of CH. Our theoretical results demonstrate that Rh is responsible for the high reactivity, while Au leads to selectivity, which may be caused by the unique intrinsic bonding properties of the metals.
