具有邻苯二甲酰亚胺发色团的金刚烷基-金刚烷 1,2-二氧杂环丁烷异构体在晶体状态化学发光性质上的差异。
Isomeric difference in the crystalline-state chemiluminescence property of an adamantylideneadamantane 1,2-dioxetane with a phthalimide chromophore.
机构信息
Department of Engineering Science, Graduate School of Informatics and Engineering, The University of Electro-Communications, Chofu, Tokyo 182-8585, Japan.
出版信息
Chem Commun (Camb). 2020 Mar 21;56(23):3369-3372. doi: 10.1039/c9cc10012a. Epub 2020 Mar 4.
Syn- and anti-isomers of an adamantylideneadamantane 1,2-dioxetane having a phthalimide side chain were prepared and investigated their crystalline-state chemiluminescence (CL) properties. The isomers showed contrastive CL properties depending on their crystal-structural characteristics, indicating that CL provides an attractive target for real-time monitoring of a chemical reaction in the crystal.
具有邻苯二甲酰亚胺侧链的金刚烷亚甲基金刚烷 1,2-二氧杂环乙烷的顺式和反式异构体被制备出来，并研究了它们在晶体状态下的化学发光（CL）性质。这些异构体表现出依赖于其晶体结构特征的对比 CL 性质，表明 CL 为实时监测晶体中化学反应提供了一个有吸引力的目标。
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