Synergistic ligand effect for the construction of titanium-oxo clusters with planar chirality and high solution stability.

作者信息

Ding Qing-Rong, Xu Gui-Lan, Zhang Jian, Zhang Lei

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.

出版信息

Dalton Trans. 2020 Apr 1;49(13):4030-4033. doi: 10.1039/d0dt00197j.

DOI:10.1039/d0dt00197j

PMID:32133475

Abstract

A synergistic effect between dimethylglyoxime (to stabilize the Ti-O ribbon) and nonlinear dicarboxylate ligands (to bend the Ti-O ribbon) has been developed to form a series of planar chiral titanium-oxo clusters with high solution stability. The charality of the obtained clusters has been studied by X-ray structural and CD spectroscopy analysis.

摘要