Ding Qing-Rong, Xu Gui-Lan, Zhang Jian, Zhang Lei
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
Dalton Trans. 2020 Apr 1;49(13):4030-4033. doi: 10.1039/d0dt00197j.
A synergistic effect between dimethylglyoxime (to stabilize the Ti-O ribbon) and nonlinear dicarboxylate ligands (to bend the Ti-O ribbon) has been developed to form a series of planar chiral titanium-oxo clusters with high solution stability. The charality of the obtained clusters has been studied by X-ray structural and CD spectroscopy analysis.
