Faculty of Chemistry, Adam Mickiewicz University in Poznan, 61-614 Poznan, Poland.
Institute for Frontier Science Initiative, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Ishikawa, Poland.
Molecules. 2020 Mar 3;25(5):1121. doi: 10.3390/molecules25051121.
Binary complexes of tartaric acid with lanthanide(III) ions were investigated. The studies have been performed in aqueous solution using the potentiometric method with computer analysis of the data for detection of the complexes set, determination of the stability constants of these compounds. The mode of the coordination of complexes found was determined using spectroscopy, which shows: Infrared, circular dichroism, ultraviolet, visible as well as luminescence spectroscopy. The overall stability constants of the complexes as well as the equilibrium constants of the reaction were determined. Analysis of the equilibrium constants of the reactions and spectroscopic data allowed the effectiveness of the carboxyl groups in the process of complex formation.
研究了酒石酸与镧系（III）离子的二元配合物。该研究是在水溶液中使用电位法并通过计算机分析数据来进行的，目的是检测配合物的存在、确定这些化合物的稳定常数。使用光谱法确定了配合物的配位模式，其中包括：红外光谱、圆二色性光谱、紫外光谱、可见光谱和荧光光谱。确定了配合物的总稳定常数以及反应的平衡常数。对反应平衡常数和光谱数据的分析表明，羧基在配合物形成过程中的有效性。
